1
COMEDK 2024 Morning Shift
MCQ (Single Correct Answer)
+1
-0

$$300 \mathrm{ml}$$ of an aqueous solution of $$\mathrm{NaOH}$$ with $$\mathrm{pH}$$ value of 10 is mixed with $$200 \mathrm{ml}$$ of an aqueous solution of $$\mathrm{HCl}$$ with a $$\mathrm{pH}$$ value of 4. What will be the $$\mathrm{pH}$$ of the resultant solution at room temperature?

A
11.262
B
10.52
C
9.301
D
8.909
2
COMEDK 2024 Morning Shift
MCQ (Single Correct Answer)
+1
-0

Aniline undergoes reactions with reagents given in the order shown

(i) Aqueous $$\mathrm{Br}_2$$

(ii) $$\mathrm{NaNO}_2 / \mathrm{HCl} / 0^0 \mathrm{C}$$

(iii) Hypophosphorous acid

What is the product formed at the end of these reactions?

A
$$1,3,5$$ - Tribromobenzene
B
$$2,4,6$$ - Tribromophenol.
C
4 -Bromoaniline
D
2-Bromoaniline
3
COMEDK 2024 Morning Shift
MCQ (Single Correct Answer)
+1
-0

Which one of the following shows the correct increasing order of basic nature of the given compounds?

A: Phenylmethanamine

B: N-Ethylethanamine

C:N, N-Dimethylaniline

D : N, N-Dimethylmethanamine

A
$$ \mathrm{B}<\mathrm{C}<\mathrm{A}<\mathrm{D} $$
B
A < D < B < C
C
D < B < A < C
D
C < A < D < B
4
COMEDK 2024 Morning Shift
MCQ (Single Correct Answer)
+1
-0

Given: $$\Delta \mathrm{G}^0{ }_{\mathrm{f}}$$ of $$\mathrm{C}_2 \mathrm{H}_2$$ is $$2.09 \times 10^5 \mathrm{~J} / \mathrm{mol}$$ and $$\Delta \mathrm{G}_{\mathrm{f}}^0$$ of $$\mathrm{C}_6 \mathrm{H}_6$$ is $$1.24 \times 10^5 \mathrm{~J} / \mathrm{mol}$$. Calculate the equilibrium constant for the cyclic polymerisation of Ethyne to Benzene at $$27^{\circ} \mathrm{C}$$. $$(\mathrm{R}=8.314 \mathrm{JK}^{-1} \mathrm{~mol}^{-1})$$

A
$$1.1134\times10^{10}$$
B
0.1113
C
$$1.429\times10^{88}$$
D
88.15
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