An unsaturated hydrocarbon $$[\mathrm{A}]$$ reacts with $$\mathrm{HBr}$$ in presence of Benzoyl peroxide to yield [B] Compound [A] when reacted with cold, dilute alkaline $$\mathrm{KMnO}_4$$ gave compound [C], 2-Methylbutane-2, 3-diol But when [A] is reacted with hot $$\mathrm{KMnO}_4$$, it yielded $$\mathrm{CH}_3 \mathrm{COOH}$$ and a compound [D] Identify compounds [A], [B] and [D]
Match the compounds given in Column I with their characteristic features listed in Column II
No. | Column I | No. | Column II |
---|---|---|---|
A | $$ \mathrm{La}(\mathrm{OH})_3 $$ |
P | Acidic in nature |
B | $$ \mathrm{Mn}_2 \mathrm{O}_7 $$ |
Q | Least basic |
C | $$ \mathrm{Lu}(\mathrm{OH}) 3 $$ |
R | Interstitial compound |
D | $$ \mathrm{Fe}_3 \mathrm{H} $$ |
S | Most basic |
Choose the group of ions / molecules in which none of the species undergo Disproportionation reaction.
What is the amount of ice that separates out on cooling a solution containing $$60 \mathrm{~g}$$ of Ethylene glycol in $$250 \mathrm{~g}$$ of water to $$-9.3^{\circ} \mathrm{C}$$ ? $$\mathrm{K}_{\mathrm{f}}$$ of $$\mathrm{H}_2 \mathrm{O}=1.86 \mathrm{~K} / \mathrm{m} ;$$ MM of ethylene glycol= $$62 \mathrm{~amu}$$