Choose the incorrect statement from the following
Given below are 4 equations showing Molar conductivities at infinite dilution of various electrolytes. Which one of them represents the correct equation?
$$\begin{aligned} & \left(\Lambda_m^0\right)_{N a B r}-\left(\Lambda_m^0\right)_{N a C l}=\left(\Lambda_m^0\right)_{\mathrm{KCl}}-\left(\Lambda_m^0\right)_{\mathrm{KBr}} \\ & \left(\Lambda_m^0\right)_{\mathrm{HCl}}+\left(\Lambda_m^0\right)_{\mathrm{KOH}}-\left(\Lambda_m^0\right)_{\mathrm{KCl}}=\left(\Lambda_m^0\right)_{\mathrm{H}_2 \mathrm{O}} \\ & \left(\Lambda_m^0\right)_{\mathrm{KBr}}-\left(\Lambda_m^0\right)_{\mathrm{NaBr}}=\left(\Lambda_m^0\right)_{\mathrm{NaBr}}-\left(\Lambda_m^0\right)_{\mathrm{Nal}} \\ & \left(\Lambda_m^0\right)_{N H_4 \mathrm{Cl}}-\left(\Lambda_m^0\right)_{\mathrm{NH}_4 \mathrm{NO}_3}=\left(\Lambda_m^0\right)_{N H_4 \mathrm{Cl}}-\left(\Lambda_m^0\right)_{N H 4 B r} \end{aligned}$$
On the basis of VSEPR theory, match the molecules listed in Column I with their shapes given in Column II.
No. | Column I | No. | Column II |
---|---|---|---|
A | $$\mathrm{ClF_3}$$ | P | Sea saw |
B | $$\mathrm{BrF_5}$$ | Q | Pentagonal bipyramidal |
C | $$\mathrm{SF_4}$$ | R | Square pyramidal |
D | $$\mathrm{IF_7}$$ | S | T-shaped |
Match the compounds given in column I with the corresponding most stable Carbocations formed by each, as given in Column II, when they undergo acidic dehydration in presence of Conc. $$\mathrm{H}_2 \mathrm{SO}_4$$.
No. | Column I | No. | Column II |
---|---|---|---|
A | 2-Methylbutan-1-ol | P | $${(C{H_3})_2}\mathop C\limits^ + - CH{(C{H_3})_2}$$ |
B | Butan-2-ol | Q | $$C{H_3} - C{H_2} - C{H_2} - \mathop C\limits^ + {H_2}$$ |
C | 3, 3-Dimethylbutan-2-ol | R | $${(C{H_3})_2}\mathop C\limits^ + - C{H_2} - C{H_3}$$ |
D | Butan-1-ol | S | $$C{H_3} - \mathop C\limits^ + H - C{H_2} - C{H_3}$$ |