1
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Which one of the following is the correct order of reagents to be used to convent [A] to [X] ?

COMEDK 2024 Evening Shift Chemistry - Aldehyde and Ketone Question 1 English

$$ \text { Reagents: } \mathrm{PCC}, \mathrm{PCl}_5, \mathrm{LiAlH}_4, \frac{\mathrm{KCN}}{\mathrm{H}_3 \mathrm{O}^{+}} $$

A
$$ \frac{K C N}{H_3 \mathrm{O}^{+}} \quad \mathrm{PCl}_5 \quad \mathrm{PCC} \quad \mathrm{LiAlH}_4 $$
B
$$ \mathrm{PCl}_5, \quad \frac{K C N}{H_3 \mathrm{O}^{+}} \quad \mathrm{LiAlH}_4 \quad \mathrm{PCC} $$
C
$$ \mathrm{LiAlH}_4, \frac{K C N}{H_3 \mathrm{O}^{+}} \quad \mathrm{PCl}_5 \quad \mathrm{PCC} $$
D
$$ \mathrm{PCC} \quad \mathrm{PCl}_5 \quad \frac{K C N}{\mathrm{H}_3 \mathrm{O}^{+}} \quad \mathrm{LiAlH}_4 $$
2
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Arrange the following redox couples in the increasing order of their reducing strength:

$$\begin{array}{ll} {[\mathrm{A}]=\mathrm{Cu} / \mathrm{Cu}^{2+}} & \mathrm{E}^0=-0.34 \mathrm{~V} \\ {[\mathrm{~B}]=\mathrm{Ag} / \mathrm{Ag}^{+}} & \mathrm{E}^0=-0.8 \mathrm{~V} \\ {[\mathrm{C}]=\mathrm{Ca} / \mathrm{Ca}^{2+}} & \mathrm{E}^0=+2.87 \mathrm{~V} \\ {[\mathrm{D}]=\mathrm{Cr} / \mathrm{Cr}^{3+}} & \mathrm{E}^0=+0.74 \mathrm{~V} \end{array}$$

A
B < A < D < C
B
A < C < B < D
C
C < D < A < B
D
D < A < C < B
3
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

In the presence of a catalyst at a given temperature of $$27^{\circ} \mathrm{C}$$, the Activation energy of a specific reaction is reduced by $$100 \mathrm{~J} / \mathrm{mol}$$. What is the ratio between the rate constants for the catalysed $$(\mathrm{k}_2)$$ and uncatalysed $$(\mathrm{k}_1)$$ reactions?

A
$$1.04 \times 10^{-2}$$
B
$$2.32 \times 10^{-2}$$
C
1.97
D
1.04
4
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

5.0 moles of an Ideal gas at 3.0 atm pressure and $$27^{\circ} \mathrm{C}$$ is compressed isothermally to half its volume by application of an external pressure of $$3.5 \mathrm{~atm}$$. What is the amount of work done (in joules) on the gas? Given: $$1 \mathrm{~L} \mathrm{~atm}=101.3 \mathrm{~J}: \mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}{ }^{-1} \mathrm{~mol}^{-1}$$

A
$$-3559.9$$
B
7268.3
C
$$-10367.4$$
D
14359.2
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