Match the Vitamins given in Column I with the diseases caused by their deficiency as given in Column II.
Vitamin | Deficiency | ||
---|---|---|---|
(A) | K | (P) | Cheilosis |
(B) | B$$_12$$ | (Q) | Osteomalacia |
(C) | B$$_2$$ | (R) | Permicious Anaemia |
(D) | D | (S) | Haemophilia |
Which one of the following is the correct order of reagents to be used to convent [A] to [X] ?
$$ \text { Reagents: } \mathrm{PCC}, \mathrm{PCl}_5, \mathrm{LiAlH}_4, \frac{\mathrm{KCN}}{\mathrm{H}_3 \mathrm{O}^{+}} $$
Arrange the following redox couples in the increasing order of their reducing strength:
$$\begin{array}{ll} {[\mathrm{A}]=\mathrm{Cu} / \mathrm{Cu}^{2+}} & \mathrm{E}^0=-0.34 \mathrm{~V} \\ {[\mathrm{~B}]=\mathrm{Ag} / \mathrm{Ag}^{+}} & \mathrm{E}^0=-0.8 \mathrm{~V} \\ {[\mathrm{C}]=\mathrm{Ca} / \mathrm{Ca}^{2+}} & \mathrm{E}^0=+2.87 \mathrm{~V} \\ {[\mathrm{D}]=\mathrm{Cr} / \mathrm{Cr}^{3+}} & \mathrm{E}^0=+0.74 \mathrm{~V} \end{array}$$
In the presence of a catalyst at a given temperature of $$27^{\circ} \mathrm{C}$$, the Activation energy of a specific reaction is reduced by $$100 \mathrm{~J} / \mathrm{mol}$$. What is the ratio between the rate constants for the catalysed $$(\mathrm{k}_2)$$ and uncatalysed $$(\mathrm{k}_1)$$ reactions?