In the presence of a catalyst at a given temperature of $$27^{\circ} \mathrm{C}$$, the Activation energy of a specific reaction is reduced by $$100 \mathrm{~J} / \mathrm{mol}$$. What is the ratio between the rate constants for the catalysed $$(\mathrm{k}_2)$$ and uncatalysed $$(\mathrm{k}_1)$$ reactions?
5.0 moles of an Ideal gas at 3.0 atm pressure and $$27^{\circ} \mathrm{C}$$ is compressed isothermally to half its volume by application of an external pressure of $$3.5 \mathrm{~atm}$$. What is the amount of work done (in joules) on the gas? Given: $$1 \mathrm{~L} \mathrm{~atm}=101.3 \mathrm{~J}: \mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}{ }^{-1} \mathrm{~mol}^{-1}$$
Identify the products C, D and F formed in the following sets of reactions.
Given below are 4 reactions. Two of these reactions will give product which is an equimolar mixture of the d and 1 forms. Identify these 2 reactions.
[A] 2- Methylpropene + $$\mathrm{HI} \rightarrow$$ ---------
[B] But-1-ene + $$\mathrm{HBr} \rightarrow$$ -----------
[C] 3-Methylbut-1-ene + $$\mathrm{HI} \rightarrow$$ -----------
[D] 3- Phenylpropene + $$\mathrm{HBr}$$ (Peroxide) $$\rightarrow$$ -----------