1
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Given are the names of 4 compounds. Two of these compounds will not undergo Cannizzaro's reaction. Identify the two.

A. 2-Chlorobutanal

B. 2,2-Dimethylpropanal

C. Benzaldehyde

D. 2-Phenyl ethanol

A
A & D
B
D & C
C
C & B
D
A & B
2
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Identify the product $$[\mathrm{C}]$$ formed at the end of the reaction below

1,1,2,2- Tetrabromopropane + 2 $$\mathrm{Zn}_{(\mathrm{S})}$$ / Ethanol $$\rightarrow$$ [B]

$$[\mathrm{B}]$$ + 2 moles of $$\mathrm{HBr} \rightarrow[\mathrm{C}]$$

A
2, 2-Dibromopropane
B
1, 1- Dibromopropane
C
1,3-Dibromopropane
D
1, 2-Dibromopropane
3
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

What is/are the product/s formed when Benzaldehyde and Ethanal react in presence of dil. $$\mathrm{NaOH}$$ followed by heating the intermediate product formed?

A
2-Methylpent-2-enal & But-2-enal
B
3-Phenylprop-2-enal & But-2-enal
C
Only product is But-2-enal
D
Only product is 2-Phenylprop-2-enal
4
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

In the estimation of element $$\mathrm{X}$$ in an organic compound, $$0.8 \mathrm{~g}$$ of the compound containing $$\mathrm{X}$$ was heated with fuming $$\mathrm{HNO}_3$$ and the cooled product was treated with barium chloride. The mass of barium sulphate precipitated was $$1.2 \mathrm{~g}$$. What is the percentage of element $$\mathrm{X}$$ and what is the formula of the violet-coloured compound formed when Lassaigne's extract of the organic compound is treated with sodium nitroprusside?

A
$$ 30.24 \quad \& \quad \mathrm{Na}_3\left[\mathrm{Fe}(\mathrm{CN})_4 \mathrm{NOS}\right] $$
B
$$ 20.6 \quad \& \quad \mathrm{Na}_4\left[\mathrm{Fe}(\mathrm{CN})_5 \mathrm{NOS}\right] $$
C
$$ 40.27 \quad \& \quad \mathrm{Na}\left[\mathrm{Fe}(\mathrm{CN})_3 \mathrm{NOS}\right] $$
D
$$ 9.156 \quad \& \quad \mathrm{Na}_3\left[\mathrm{Fe}(\mathrm{CN})_5 \mathrm{NO}\right] $$
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