1
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Identify the final product $$[\mathrm{D}]$$ formed when Benzyl alcohol undergoes the following series of reactions

$$\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{OH}+\mathrm{SOCl}_2 \rightarrow[\mathrm{A}]+\mathrm{KCN} \rightarrow[\mathrm{B}]+\mathrm{H}_3 \mathrm{O}^{+} \text {(partial hydrolysis) } \rightarrow[\mathrm{C}]+\mathrm{H}_3 \mathrm{O}^{+} \text {(complete hydrolysis) } \rightarrow[\mathrm{D}]$$

A
4-Chlorobenzoic acid
B
Benzoic acid
C
2-Chlorobenzoic acid
D
2-Phenylethanoic acid
2
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Choose the incorrect statement from the following:

A. Isoelectronic molecules/ions have the same bond order.

B. Dipole moment of $$\mathrm{NH}_3$$ is greater than that of $$\mathrm{NF}_3$$.

C. The Carbon in Methyl Carbocation is $$\mathrm{sp}^3$$ hybridised.

D. The stability of an ionic compound is measured in terms of its lattice enthalpy and not simply based on attaining Octet configuration.

A
C
B
A
C
D
D
B
3
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Based on Crystal Field theory, match the Complex ions listed in Column I with the electronic configuration in the d orbitals of the central metal ion listed in Column II.

No. Complexion No. d orbital configuration of central metal ion.
(A) $$
\left[M n(C N)_6\right]^{4-}
$$
(P) $$
e_g^2 t_{2 g}^3
$$
(B) $$
\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}
$$
(Q) $$
t_{2 g}^4 e_g^2
$$
(C) $$
\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}
$$
(R) $$
t_{2 g}^5
$$
(D) $$
\left[\mathrm{MnCl}_4\right]^{2-}
$$
(S) $$
t_{2 g}^5 e_g^2
$$

A
$$ \mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{Q} $$
B
$$ \mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P} $$
C
$$ \mathrm{A}=\mathrm{Q} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{R} $$
D
$$ \mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{S} \quad \mathrm{C}=\mathrm{P} \quad \mathrm{D}=\mathrm{Q} $$
4
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

The Activation energy for the reaction $$A \rightarrow B+C$$, at a temperature $$\mathrm{TK}$$ was $$0.04606 \mathrm{~RT} \mathrm{~J} / \mathrm{mol}$$. What is the ratio of Arrhenius factor to the Rate constant for this reaction?

A
1.585
B
$$3.2 \times 10^{-2}$$
C
$$1.047 \times 10^{-2}$$
D
1.047
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