Identify the final product $$[\mathrm{D}]$$ formed when Benzyl alcohol undergoes the following series of reactions
$$\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{OH}+\mathrm{SOCl}_2 \rightarrow[\mathrm{A}]+\mathrm{KCN} \rightarrow[\mathrm{B}]+\mathrm{H}_3 \mathrm{O}^{+} \text {(partial hydrolysis) } \rightarrow[\mathrm{C}]+\mathrm{H}_3 \mathrm{O}^{+} \text {(complete hydrolysis) } \rightarrow[\mathrm{D}]$$
Choose the incorrect statement from the following:
A. Isoelectronic molecules/ions have the same bond order.
B. Dipole moment of $$\mathrm{NH}_3$$ is greater than that of $$\mathrm{NF}_3$$.
C. The Carbon in Methyl Carbocation is $$\mathrm{sp}^3$$ hybridised.
D. The stability of an ionic compound is measured in terms of its lattice enthalpy and not simply based on attaining Octet configuration.
Based on Crystal Field theory, match the Complex ions listed in Column I with the electronic configuration in the d orbitals of the central metal ion listed in Column II.
No. | Complexion | No. | d orbital configuration of central metal ion. |
---|---|---|---|
(A) | $$ \left[M n(C N)_6\right]^{4-} $$ |
(P) | $$ e_g^2 t_{2 g}^3 $$ |
(B) | $$ \left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+} $$ |
(Q) | $$ t_{2 g}^4 e_g^2 $$ |
(C) | $$ \left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+} $$ |
(R) | $$ t_{2 g}^5 $$ |
(D) | $$ \left[\mathrm{MnCl}_4\right]^{2-} $$ |
(S) | $$ t_{2 g}^5 e_g^2 $$ |
The Activation energy for the reaction $$A \rightarrow B+C$$, at a temperature $$\mathrm{TK}$$ was $$0.04606 \mathrm{~RT} \mathrm{~J} / \mathrm{mol}$$. What is the ratio of Arrhenius factor to the Rate constant for this reaction?