Which of the following 2 compounds exhibit both Geometrical and Structural isomerism?
$$\begin{aligned} & \mathrm{A}=\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] \mathrm{NO}_2 \\ & \mathrm{~B}=\left[\mathrm{Co}\left(\mathrm{NH}_3\right) \mathrm{Br}\right] \mathrm{SO}_4 \\ & \mathrm{C}=\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3\left(\mathrm{NO}_2\right)_3\right] \\ & \mathrm{D}=\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_3 \end{aligned}$$
What is the wave number (Units $$\mathrm{cm}^{-1}$$) of the longest wave length transition in the Balmer series of Hydrogen spectrum? $$Z=1 \text { for } H$$
Given below are 2 statements: Assertion and Reason. Choose the correct option.
Assertion: When Molar conductivity for a strong electrolyte is plotted versus $$\sqrt{C}(\mathrm{~mol} / \mathrm{L})^{1 / 2}$$, a straight line is obtained with intercept equal to Molar conductivity at infinite dilution for the electrolyte and Slope equal to $$-\mathrm{A}$$. All electrolytes of a given type have the same $$\mathrm{A}$$ value.
Reason: At infinite dilution, strong electrolytes of the same type will have different number of ions due to incomplete dissociation.
Based on Valence Bond Theory, match the complexes listed in Column I with the number of unpaired electrons on the central metal ion, given in Column II
No. | Complex ions | No. | Number of unpaired electrons |
---|---|---|---|
(A) | $$ \left[\mathrm{Fe} \mathrm{F}_6\right]^{3-} $$ |
(P) | 0 |
(B) | $$ \left[\mathrm{Fe}(\mathrm{CN})_6\right]^{4-} $$ |
(P) | 1 |
(C) | $$ \left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+} $$ |
(R) | 5 |
(D) | $$ \left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-} $$ |
(S) | 4 |