An inorganic compound $$\mathrm{W}$$ undergoes the following reactions:
$$ \begin{gathered} W+\frac{\mathrm{Na}_2 \mathrm{CO}_3}{\mathrm{O}_2 / \text { heat }} \rightarrow X+\frac{\mathrm{H}^{+}}{} \rightarrow Y_{(s)} \\ Y(a q)+\mathrm{KCl}(\mathrm{aq}) \rightarrow Z_{(S)} \end{gathered} $$
Z appears in the form of orange crystals and is used as an oxidising agent in acid medium. Identify the compound W.
Given are the names of 4 compounds. Two of these compounds will not undergo Cannizzaro's reaction. Identify the two.
A. 2-Chlorobutanal
B. 2,2-Dimethylpropanal
C. Benzaldehyde
D. 2-Phenyl ethanol
Identify the product $$[\mathrm{C}]$$ formed at the end of the reaction below
1,1,2,2- Tetrabromopropane + 2 $$\mathrm{Zn}_{(\mathrm{S})}$$ / Ethanol $$\rightarrow$$ [B]
$$[\mathrm{B}]$$ + 2 moles of $$\mathrm{HBr} \rightarrow[\mathrm{C}]$$
What is/are the product/s formed when Benzaldehyde and Ethanal react in presence of dil. $$\mathrm{NaOH}$$ followed by heating the intermediate product formed?