1
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Match the names of reactions given in Column I with the appropriate reactions given in Column II.

No. Name of reaction No. Equations representing reactions
(A) Sandmeyer (P) $$
2 \mathrm{C}_6 \mathrm{H}_5 \mathrm{Cl}+\mathrm{Na} \text { (dry ether) } \rightarrow \text { Diphenyl. }
$$
(B) Fittig (Q) $$
\mathrm{CH}_3-\mathrm{CHBr}-\mathrm{CH}_3+\mathrm{AgF} \rightarrow \mathrm{CH}_3-\mathrm{CHF}-\mathrm{CH}_3+\mathrm{AgBr}
$$
(C) Swarts (R) $$
\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{Br}+\mathrm{Nal} \text { ( Acetone) } \rightarrow \mathrm{CH}_3-\mathrm{CH}_2-\mathrm{I}+\mathrm{NaBr}
$$
(D) Finkelstein (S) $$
\mathrm{C}_6 \mathrm{H}_5 \mathrm{~N}_2+\mathrm{Cl}-+\mathrm{Cu}_2 \mathrm{Br}_2 / \mathrm{HBr} \rightarrow \mathrm{C}_6 \mathrm{H}_5 \mathrm{Br}+\mathrm{N}_2
$$

A
$$ \mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{R} $$
B
$$ \mathrm{A}=\mathrm{Q} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{P} $$
C
$$ \mathrm{A}=\mathrm{S} \quad \mathrm{B}=\mathrm{R} \quad \mathrm{C}=\mathrm{Q} \quad \mathrm{D}=\mathrm{P} $$
D
$$ \mathrm{A}=\mathrm{R} \quad \mathrm{B}=\mathrm{P} \quad \mathrm{C}=\mathrm{S} \quad \mathrm{D}=\mathrm{Q} $$
2
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

With reference to Pauling's Electronegativity scale, which one of the following options shows the correct order of electronegativity values of elements?

A
$$\mathrm{Na}>\mathrm{Cs}>\mathrm{K}$$
B
$$\mathrm{Mg}>\mathrm{Al}>\mathrm{Si}$$
C
$$\mathrm{B}>\mathrm{C}>\mathrm{Al}$$
D
$$\mathrm{N}>\mathrm{S}>\mathrm{P}$$
3
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

What volume of $$0.2 \mathrm{~M}$$ Acetic acid is to be added to $$100 \mathrm{ml}$$ of $$0.4 \mathrm{M}$$ Sodium acetate so that a Buffer solution of $$\mathrm{pH}$$ equal to 4.94 is obtained? $$(\mathrm{pK}_{\mathrm{a}}$$ of $$\mathrm{CH}_3 \mathrm{COOH}=4.76)$$

A
132.1 ml
B
125.3 ml
C
150.2 ml
D
110.6 ml
4
COMEDK 2024 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Arrange the compounds $$\mathrm{A}, \mathrm{B}, \mathrm{C}$$ and $$\mathrm{D}$$ in the increasing order of their reactivity towards $$\mathrm{S_N}1$$ reaction.

$$ \begin{aligned} & \mathrm{A}=\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{Cl} \\ & \mathrm{B}=\mathrm{C}_6 \mathrm{H}_5 \mathrm{Cl} \\ & \mathrm{C}=\mathrm{CH}_2=\mathrm{CH}-\mathrm{Cl} \\ & \mathrm{D}=\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{Cl} \end{aligned}$$

A
$$\mathrm{D}<\mathrm{B}<\mathrm{A}<\mathrm{C}$$
B
$$\mathrm{D}<\mathrm{C}<\mathrm{B}<\mathrm{A}$$
C
$$\mathrm{B}<\mathrm{D}<\mathrm{C}<\mathrm{A}$$
D
$$\mathrm{C}<\mathrm{A}<\mathrm{D}<\mathrm{B}$$
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