Which one of the following propositional logic formulas is TRUE when exactly two of $$p, q,$$ and $$r$$ are TRUE?

Let S denote the set of all functions $$f:\,{\{ 0,\,1\} ^4}\, \to \,\{ 0,\,1\} $$. Denote by N the number of functions from S to the set {0, 1}. The value of $${\log _2}$$ $${\log _2}$$ N is___________________

Four fair six-sided dice are rolled. The probability that the sum of the results being 22 is X/1296. The value of X is__________

Let the function
$$f\left( \theta \right) = \left| {\matrix{ {\sin \,\theta } & {\cos \,\theta } & {\tan \,\theta } \cr {\sin \left( {{\pi \over 6}} \right)} & {\cos \left( {{\pi \over 6}} \right)} & {\tan \left( {{\pi \over 6}} \right)} \cr {\sin \left( {{\pi \over 3}} \right)} & {\cos \left( {{\pi \over 3}} \right)} & {\tan \left( {{\pi \over 3}} \right)} \cr } } \right|$$

Where $$\theta \in \left[ {{\pi \over 6},{\pi \over 3}} \right]$$ and $$f\left( \theta \right)$$ denote the derivative of $$f$$ with repect to $$\theta $$. Which of the following statements is/are TRUE?

$${\rm I})$$ There exists $$\theta \in \left[ {{\pi \over 6},{\pi \over 3}} \right]$$ such that $$f\left( \theta \right)$$ $$= 0$$.
$${\rm I}{\rm I})$$ There exists $$\theta \in \left[ {{\pi \over 6},{\pi \over 3}} \right]$$ such that $$f\left( \theta \right)$$ $$ \ne 0$$.