Rank the following anions in order of decreasing nucleophilicity in a polar protic solvent (most → least nucleophilic).

$3>2>1$
$2>3>1$
$1>3>2$
$2>1>3$
In which of the following species, $\mathrm{sp}^3 \mathrm{~d}^2$ hybridisation is not associated?
$\mathrm{XeF}_6$
$\mathrm{BrF}_6^{+}$
$\mathrm{IF}_5$
$\mathrm{XeF}_4$
For the reaction $A \rightarrow B$ ,variation of concentration is plotted against time as shown below.

Which of the following statements is true?
Region(1)indicates equilibrium
Region(2)indicates equilibrium
Region(3)indicates equilibrium
Both the Regions(2)and(3)indicate equilibrium
In a first order reaction,the concentration of reactant decreases from 400 moles lit $^{-1}$ to 50 moles lit ${ }^{-1}$ in $7 \cdot 5 \times 10^3 \mathrm{~s}$ .The rate constant of the reaction is(approximately)
$1 \times 10^{-2} \mathrm{~s}^{-1}$
$2.5 \times 10^{-3} \mathrm{~s}^{-1}$
$1 \times 10^{-5} \mathrm{~s}^{-1}$
$2.77 \times 10^{-4} \mathrm{~s}^{-1}$
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