A buffer solution contains 100 ml of $0.01(\mathrm{M}) \mathrm{CH}_3 \mathrm{COOH}$ and 200 ml of $0.02(\mathrm{M}) \mathrm{CH}_3 \mathrm{COONa}_a .700 \mathrm{ml}$ of water is added subsequently to the buffer solution.The pH before and after dilution are [given,$p K_a=4.74 ; \log 2=0.301$ ]
$5.04,5.04$
$5 \cdot 04,0 \cdot 504$
$5 \cdot 04,1 \cdot 54$
$5 \cdot 34,5 \cdot 34$
The correct order of conductivity of $0.001(\mathrm{M})$ separate aqueous solutions of $\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_6\right] \mathrm{Cl}_4(\mathrm{i})$; $\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_6\right] \mathrm{Cl}_3$ (ii); $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] \mathrm{Cl}$ (iii) and $\mathrm{K}_2 \mathrm{PtCl}_6$ (iv) each containing octahedral complex species is
(i) < (ii) < (iii) < (iv)
(i) < (ii) < (iv) < (iii)
(i) $<$ (iv) $<$ (iii) $<$ (ii)
(iii) $<$ (iv) $<$ (ii) $<$ (i)
Borazole is prepared by heating the product isolated by reacting
boron with dinitrogen.
diborane with ammonium nitrate.
diborane with ammonia.
boron with ammonia.
The increasing order of basicity of the following compounds is

I $<$ III $<$ II
III $<$ I $<$ II
II $<$ I $<$ III
II $<$ III $<$ I
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