Which one of the following Coordination entities exhibits Facial and Meridional isomerism?
Arrange the following in the decreasing order of their Dipole moments.
a. Chlorobenzene
b. 1,2-Dichlorobenzene
c. 1,3-Dichlorobenzene
d. 1,4-Dichlorobenzene.
The reactions taking place with $$\mathrm{2- Phenyl-2-bromopropane}$$ as the starting material is shown below. Identify [A] and [B] formed in the reaction.
$$ \mathrm{C}_6 \mathrm{H}_5-\mathrm{C}\left(\mathrm{CH}_3\right)_2^{-} \mathrm{Br} \xrightarrow[\Delta]{\text { KOH Alcoholic }}[\mathrm{A}] $$
$$ [\mathrm{A}]+\mathrm{HBr} \xrightarrow{\left(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CO})_2 \mathrm{O}\right.}[\mathrm{B}]$$
The reaction taking place in a galvanic cell is as given
$$\mathrm{A}(\mathrm{s})+\mathrm{B}^{2+}\left(\mathbf{1} \mathbf{1} \mathbf{1 0} \mathbf{0}^{-\mathrm{M}} \mathbf{M}\right) \rightarrow \mathrm{B}_{(\mathrm{s})}+\mathrm{A}^{2+}(0.1 \mathrm{M}).$$
The emf of the cell is $$+2.651 \mathrm{~V}$$. If the standard emf of the cell is $$+2.71 \mathrm{~V}$$, what is the value of $$\mathrm{X}$$ ?