1
COMEDK 2023 Evening Shift
MCQ (Single Correct Answer)
+1
-0

If electrolysis of water is carried out for a time duration of 2 hours, how much electric current in amperes would be required to liberate $$100 \mathrm{~ml}$$ of $$\mathrm{O}_2$$ gas measured under standard conditions of temperature and pressure?

A
0.1723 A
B
4.178 A
C
0.8616 A
D
0.2393 A
2
COMEDK 2023 Evening Shift
MCQ (Single Correct Answer)
+1
-0

For a reaction of the type, $$2 \mathrm{X}+\mathrm{Y} \rightarrow \mathrm{A}+\mathrm{B}$$, the following is the data collected:

Experiment $$\mathrm{[X]}$$ $$\mathrm{[Y]}$$ Initial rate of formation of A
1 0.2 0.2 $$12.0\times10^{-3}$$
2 0.6 0.4 $$\mathrm{14.4\times10^{-2}}$$
3 0.6 0.8 $$5.76\times10^{-1}$$
4. 0.8 0.2 $$\mathrm{4.8\times10^{-2}}$$

What is the overall order of the reaction?

A
2.5
B
3
C
2
D
1.5
3
COMEDK 2023 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Select the strongest base from the given compounds:

[A] p- $$\mathrm{NO}_2-\mathrm{C}_6 \mathrm{H}_4 \mathrm{NH}_2$$

[B] $$\mathrm{C}_6 \mathrm{H}_5-\mathrm{CH}_2-\mathrm{NH}_2$$

[C] $$\mathrm{m}-\mathrm{NO}_2-\mathrm{C}_6 \mathrm{H}_4 \mathrm{NH}_2$$

[D] $$\mathrm{C}_6 \mathrm{H}_5 \mathrm{NH}_2$$

A
[A]
B
[C]
C
[B]
D
[D]
4
COMEDK 2023 Evening Shift
MCQ (Single Correct Answer)
+1
-0

The conversion of Propyne to Benzene can be brought out in 4 steps.

Choose the reagents to be used, in the proper sequential order, to bring out the conversion.

Reagents provided: alc. $$\mathrm{KOH}, \mathrm{H}_2 / \mathrm{Pd}, \mathrm{Na} /$$ dry ether, $$\mathrm{HBr}, \mathrm{HBr} /\left(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CO}\right)_2 \mathrm{O}_2$$, Soda-lime, $$\mathrm{Cr}_2 \mathrm{O}_3$$ (high T and P), Conc. $$\mathrm{H}_2 \mathrm{SO}_4$$

A
$$\mathrm{Na} /$$ Ether, $$\mathrm{Cr}_2 \mathrm{O}_3$$ (high $$\mathrm{T}$$ and $$\mathrm{P}$$), $$\mathrm{HBr}, \mathrm{H}_2 / \mathrm{Pd}$$
B
$$\mathrm{HBr}$$, alc. $$\mathrm{KOH}, \mathrm{HBr} /\left(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CO}\right)_2 \mathrm{O}_2, \mathrm{Cr}_2 \mathrm{O}_3$$ (high $$\mathrm{T}$$ and $$\mathrm{P}$$)
C
$$\mathrm{Cr}_2 \mathrm{O}_3$$ (high $$\mathrm{T}$$ and $$\mathrm{P}$$), $$\mathrm{Na} /$$ dry ether, $$\mathrm{HBr}$$, Conc. $$\mathrm{H}_2 \mathrm{SO}_4$$
D
$$\mathrm{H}_2 / \mathrm{Pd}, \mathrm{HBr} /\left(\mathrm{C}_6 \mathrm{H}_5 \mathrm{CO}\right)_2 \mathrm{O}_2, \mathrm{Na} /$$ dry ether, $$\mathrm{Cr}_2 \mathrm{O}_3$$ (high $$\mathrm{T}$$ and $$\mathrm{P}$$)
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