1
COMEDK 2023 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Match the following characteristics of transition metals given in Column I with the examples listed in Column II

S. No. Characteristic properties S. No. Examples
W Chemically inert, non-stoichiometric compound A $$\mathrm{WO}_3$$
X Higher oxidation states are more stable B $$\mathrm{TiCl_4}$$
Y Due to inert pair effect, lower oxidation state is more stable C $$\mathrm{Mn_4N}$$
Z. Colourless compound of transition metal D $$\mathrm{SnCl_2}$$

A
$$ \mathrm{W}=\mathrm{B} \quad \mathrm{X}=\mathrm{C} \quad \mathrm{Y}=\mathrm{D} \quad \mathrm{Z}=\mathrm{A} $$
B
$$ \mathrm{W}=\mathrm{C} \quad \mathrm{X}=\mathrm{D} \quad \mathrm{Y}=\mathrm{A} \quad \mathrm{Z}=\mathrm{B} $$
C
$$ \mathrm{W}=\mathrm{C} \quad \mathrm{X}=\mathrm{A} \quad \mathrm{Y}=\mathrm{D} \quad \mathrm{Z}=\mathrm{B} $$
D
$$ \mathrm{W}=\mathrm{A} \quad \mathrm{X}=\mathrm{D} \quad \mathrm{Y}=\mathrm{C} \quad \mathrm{Z}=\mathrm{B} $$
2
COMEDK 2023 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Gaseous Nitrous oxide decomposes at $$298 \mathrm{~K}$$ to form Nitrogen gas and Oxygen gas. The $$\Delta \mathbf{H}$$ for the reaction at $$1.0 \mathrm{~atm}$$ pressure and $$298 \mathrm{~K}$$ is $$\mathbf{- 1 6 3 . 1 5} \mathbf{~ k J}$$. Calculate Internal energy change for the decomposition of $$100 \mathrm{~g}$$ of Nitrous oxide gas under the same conditions of temperature and pressure.

A
$$-166$$ kJ
B
$$-188.2$$ kJ
C
$$-230.3$$ kJ
D
$$-376.43$$ kJ
3
COMEDK 2023 Evening Shift
MCQ (Single Correct Answer)
+1
-0

In neutral medium $$\mathrm{KMnO}_4$$ oxidises $$\mathrm{MnSO}_4$$ to _________

A
$$\mathrm{Mn}_2 \mathrm{O}_3$$
B
$$\mathrm{Mn}_3 \mathrm{O}_4$$
C
$$\mathrm{MnO}_2$$
D
$$\mathrm{K}_2 \mathrm{MnO}_4$$
4
COMEDK 2023 Evening Shift
MCQ (Single Correct Answer)
+1
-0

What would be the van't Hoff factor for a solution prepared by dissolving $$3.42 \mathrm{~g}$$ of $$\mathrm{CaCl}_2$$ in $$2500 \mathrm{~ml}$$ of water having an Osmotic pressure equal to $$0.75 \mathrm{~atm}$$. at $$27^{\circ} \mathrm{C}$$ ? Molar mass of $$\mathrm{CaCl}_2=111 \mathrm{~amu}$$.

A
2.7
B
3.15
C
2.47
D
3.0
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