1
COMEDK 2023 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Which one of the following is an incorrect statement pertaining to the properties of Coordination compounds?

A
A square planar complex of the type Mabcd, where a, b, c and d are unidentate ligands, exhibits geometrical isomerism and exists in one cis-form and two trans-forms.
B
[$$\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{NO}_2$$] Cl2 exists in 2 forms, the red form and the yellow form which are linkage isomers.
C
$$\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}$$ is called a Low spin complex.
D
Out of cis- $$\left[\mathrm{CrCl}_2(\mathrm{ox})_2\right]^{3-}$$ and trans- $$\left[\mathrm{CrCl}_2(\mathrm{ox})_2\right]^{3-}$$, the trans isomer is optically inactive.
2
COMEDK 2023 Evening Shift
MCQ (Single Correct Answer)
+1
-0

$$\mathrm{X}$$ is an electrolyte with a concentration of $$0.04 \mathrm{M}$$ whose formula is of the type $$\mathrm{X}_2 \mathrm{~A}$$. $$\mathrm{Y}$$ is a non-electrolyte solution with a concentration of $$0.2 \mathrm{M}$$ and has an osmotic pressure equal to $$\mathrm{P}_2$$ at room temperature. What is the relationship between the Osmotic pressure $$\pi$$ of $$\mathrm{X}$$ and $$\mathrm{P}_2$$ ?

A
$$\pi=0.6 P_2$$
B
$$\pi=0.12 \mathrm{P}_2$$
C
$$\pi=0.04 \mathrm{P}_2$$
D
$$\pi=0.8 P_2$$
3
COMEDK 2023 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Identify the catalyst used in the reaction between Iodide and persulphate ions.

$$2 \mathrm{I}^{-}+\mathrm{S}_2 \mathrm{O}_8{ }^{2-} \rightarrow \mathrm{I}_2+2 \mathrm{SO}_4{ }^{2-}$$

A
$$\mathrm{Cr}^{3+}$$
B
$$\mathrm{Fe}^{3+}$$
C
$$\mathrm{Ni}^{2+}$$
D
$$\mathrm{Fe}^{2+}$$
4
COMEDK 2023 Evening Shift
MCQ (Single Correct Answer)
+1
-0

Find the correct matches of the substances, given in Column I, from their characteristic properties given in Column II.

S.No. Column I S.No. Column II
W $$
\mathrm{Tl}
$$
A Decomposes steam to form its dioxide and dihydrogen gas.
X $$
\mathrm{CCl}_4
$$
B Consists of twenty 6 -membered rings and twelve 5 membered rings.
Y $$\mathrm{Tin}$$ C +3 oxidation state is highly oxidising.
Z $$
\mathrm{C_{60}}
$$
D Electron precise species, neither acts as electron donor nor as electron acceptor.

A
$$ \mathrm{W}=\mathrm{C} \quad \mathrm{X}=\mathrm{D} \quad \mathrm{Y}=\mathrm{A} \quad \mathrm{Z}=\mathrm{B} $$
B
$$ \mathrm{W}=\mathrm{B} \quad \mathrm{X}=\mathrm{D} \quad \mathrm{Y}=\mathrm{C} \quad \mathrm{Z}=\mathrm{A} $$
C
$$ \mathrm{W}=\mathrm{D} \quad \mathrm{X}=\mathrm{C} \quad \mathrm{Y}=\mathrm{A} \quad \mathrm{Z}=\mathrm{B} $$
D
$$ \mathrm{W}=\mathrm{D} \quad \mathrm{X}=\mathrm{C} \quad \mathrm{Y}=\mathrm{B} \quad \mathrm{Z}=\mathrm{A} $$
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