Solute '$$X$$' dimerises in water to the extent of $$80\%$$. 2.5g of '$$X$$' in $$100 \mathrm{~g}$$ of water increases the boiling point by $$0.3^{\circ} \mathrm{C}$$. The molar mass of 'X' is $$[K_b=0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}]$$

A non-volatile solute, '$$A$$' tetramerises in water to the extent of $$80 \%.$$ $$2 .5 \mathrm{~g}$$ of '$$A$$' in $$100 \mathrm{~g}$$ of water, lower the freezing point by $$0.3^{\circ} \mathrm{C}$$. The molar mass of '$$A$$' in $$\mathrm{g}$$ is $$\left(K_f\right.$$ for water $$=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1})$$

Solution '$$A$$' contains acetone dissolved in chloroform and solution '$$B$$' contains acetone dissolved in carbon disulphide. The type of deviations from Raoult's law shown by solutions $$A$$ and $$B$$, respectively are

Relative lowering of vapour pressure of a dilute solution of glucose dissolved in $$1 \mathrm{~kg}$$ of water is 0.002 . The molality of the solution is