Coordination Compounds · Chemistry · KCET

On treating 100 mL of 0.1 M aqueous solution of the complex $\mathrm{CrCl}_3 \cdot 6 \mathrm{H}_2 \mathrm{O}$ with excess of $\mathrm{AgNO}_3, 2.86 \mathrm{~g}$ of AgCl was obtained. The complex is

The complex compounds $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{SO}_4\right] \mathrm{Br}$ and $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Br}\right] \mathrm{SO}_4$ are

Which of the following statements are true about $\left[\mathrm{CoF}_6\right]^{3-}$ ion ?

I. The complex has octahedral geometry.

II. Coordination number of Co is 3 and oxidation state is +6 .

III. The complex is $s p^3 d^2$ hybridised.

IV. It is a high spin complex.

If a didentate ligand ethane-1, 2-diamine is progressively added in the molar ratio en : Ni :: 1: 1, 2 : 1, 3 : 1 to $$\left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$$ aq solution, following co-ordination entities are formed.

I. $$\left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_4 \mathrm{en}\right]^{2+}(a q)$$ - pale blue

II. $$\left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_2(\mathrm{en})_2\right]^{2+}(\mathrm{aq})$$ - blue/purple

III. $$\left[\mathrm{Ni}(\mathrm{en})_3\right]^{2+}(\mathrm{aq})$$ - violet

The wavelength in $$\mathrm{nm}$$ of light absorbed in case of I and III are respectively

Which of the following is an organometallic compound

When $$\mathrm{FeCl}_3$$ is added to excess of hot water gives a sol '$$X$$'. When $$\mathrm{FeCl}_3$$ is added to $$\mathrm{NaOH}(a q)$$ solution, gives sol '$$Y$$'

$$X$$ and $$Y$$ formed in the above processes respectively are

Which formula and name combination is incorrect?

Which of the following system in an octahedral complex has maximum unpaired electrons?

The correct IUPAC name of cis-platin is

Crystal field splitting energy (CFSE) for $$\left[\mathrm{CoCl}_6\right]^{4-}$$ is $$18000 \mathrm{~cm}^{-1}$$. The crystal field splitting energy (CFSE) for $$\left[\mathrm{CoCl}_4\right]^{2-}$$ will be

The complex hexamineplatinum(IV)chloride will give _____ number of ions on ionisation.

For the crystal field splitting in octahedral complexes,

The IUPAC name of $$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{CO}_3\right)\right] \mathrm{Cl}$$ is

Homoleptic complexes among the following are

(A) $$\mathrm{K}_3\left[\mathrm{Al}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]$$

(B) $$\left[\mathrm{CoCl}_2(\mathrm{en})_2\right]^{+}$$

(C) $$\mathrm{K}_2\left[\mathrm{Zn}(\mathrm{OH})_4\right]$$

The correct order for wavelengths of light absorbed in the complex ions $$\left[\mathrm{CoCl}\left(\mathrm{NH}_3\right)_5\right]^{2+},\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}$$ and $$\left[\mathrm{Co}(\mathrm{CN})_6\right]^{3-}$$ is

The coordination number of $$\mathrm{Fe}$$ and $$\mathrm{Co}$$ in the complex ions, $$\left.\mathrm{Fe}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}$$ and $$\left[\mathrm{Co}(\mathrm{SCN})_4\right]^{2-}$$ are respectively

Number of stereoisomers exhibited by $$\left[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2\right]^{+}$$ is

Give the IUPAC name of $$\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_4\right]\left[\mathrm{Pt} \mathrm{Cl}_4\right]$$ is

Which among the following is the strongest ligand?

The formula of pentaaquanitratochromium (III) nitrate is,