Liquid Solution · Chemistry · KCET

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MCQ (Single Correct Answer)

1

Among the following 0.1 m aqueous solutions, which one will exhibit the lowest boiling point elevation, assuming complete ionization of the compound in solution?

KCET 2025
2

Variation of solubility with temperature t for a gas in liquid is shown by the following graphs. The correct representation is

KCET 2025
3

180 g of glucose, $\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6$, is dissolved in 1 kg of water in a vessel. The temperature at which water boils at 1.013 bar is _________ (given, $\mathrm{K}_{\mathrm{b}}$ for water is $052 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$. Boiling point for pure water is 373.15 K )

KCET 2025
4

If $N_2$ gas is bubbled through water at 293 K , how many moles of $N_2$ gas would dissolve in 1 litre of water? Assume that $\mathrm{N}_2$ exerts a partial pressure of 0.987 bar.

[Given $\mathrm{K}_{\mathrm{H}}$ for $\mathrm{N}_2$ at 293 K is 76.48 K bar ]

KCET 2025
5

Vapour pressure of a solution containing 18 g of glucose and 178.2 g of water at $100^{\circ} \mathrm{C}$ is (Vapour pressure of pure water at $100^{\circ} \mathrm{C}=760$ torr)

KCET 2024
6

A mixture of phenol and aniline shows negative deviation from Raoult's law. This is due to the formation of

KCET 2024
7

Which one of the following pairs will show positive deviation from Raoult's law?

KCET 2024
8

For which one of the following mixtures is composition uniform throughout?

KCET 2024
9

The swelling in feet and ankles of an aged person due to sitting continuously for long hours during travel, is reduced by soaking the feet in warm salt water. This is because of

KCET 2023
10

A sample of water is found to contain $$5.85 \%$$ $$\left(\frac{w}{w}\right)$$ of $$A B$$ (molecular mass 58.5 ) and $$9.50 \%$$ $$\left(\frac{w}{w}\right) X Y_2$$ (molecular mass 95). Assuming $$80 \%$$ ionisation of $$A B$$ and $$60 \%$$ ionisation of $$X Y_2$$, the freezing point of water sample is [Given, $$K_f$$ for water $$1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$, Freezing point of pure water is $$273 \mathrm{~K}$$ and $$A, B$$ and $$Y$$ are monovalent ions.]

KCET 2023
11

Solubility of a gas in a liquid increases with

KCET 2022
12

The rise in boiling point of a solution containing $$1.8 \mathrm{~g}$$ of glucose in $$100 \mathrm{~g}$$ of solvent is $$0.1^{\circ} \mathrm{C}$$. The molal elevation constant of the liquid is

KCET 2022
13

If $$3 \mathrm{~g}$$ of glucose (molar mass $$=180 \mathrm{~g}$$) is dissolved in $$60 \mathrm{~g}$$ of water at $$15^{\circ} \mathrm{C}$$, the osmotic pressure of the solution will be

KCET 2022
14

Which of the following colligative properties can provide molar mass of proteins, polymers and colloids with greater precision?

KCET 2022
15

Henry's law constant for the solubility of $$\mathrm{N}_2$$ gas in water at $$298 \mathrm{~K}$$ is $$1.0 \times 10^5 \mathrm{~atm}$$. The mole fraction of $$\mathrm{N}_2$$ in air is 0.8 . The number of moles of $$\mathrm{N}_2$$ from air dissolved in 10 moles of water at $$298 \mathrm{~K}$$ and $$5 \mathrm{~atm}$$ pressure is

KCET 2021
16

Choose the correct statement.

KCET 2021
17

The $$K_{\mathrm{H}}$$ value ($$\mathrm{K}$$ bar) of argon (I), carbondioxide (II), formaldehyde (III) and methane (IV) are respectively $$40.3,167, 1.83 \times 0^{-5}$$ and 0.413 at $$298 \mathrm{~K}$$. The increasing order of solubility of gas in liquid is

KCET 2021
18

The vapour pressure of pure liquids $$A$$ and $$B$$ are 450 and $$700 \mathrm{~mm}$$ of $$\mathrm{Hg}$$ at $$350 \mathrm{~K}$$ respectively. If the total vapour pressure of the mixture is $$600 \mathrm{~mm}$$ of $$\mathrm{Hg}$$, the composition of the mixture in the solution is

KCET 2021
19

Which of the following pair of solutions is isotonic?

KCET 2020
20

Solute '$$X$$' dimerises in water to the extent of $$80\%$$. 2.5g of '$$X$$' in $$100 \mathrm{~g}$$ of water increases the boiling point by $$0.3^{\circ} \mathrm{C}$$. The molar mass of 'X' is $$[K_b=0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}]$$

KCET 2020
21

A non-volatile solute, '$$A$$' tetramerises in water to the extent of $$80 \%.$$ $$2 .5 \mathrm{~g}$$ of '$$A$$' in $$100 \mathrm{~g}$$ of water, lower the freezing point by $$0.3^{\circ} \mathrm{C}$$. The molar mass of '$$A$$' in $$\mathrm{g}$$ is $$\left(K_f\right.$$ for water $$=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1})$$

KCET 2019
22

Solution '$$A$$' contains acetone dissolved in chloroform and solution '$$B$$' contains acetone dissolved in carbon disulphide. The type of deviations from Raoult's law shown by solutions $$A$$ and $$B$$, respectively are

KCET 2019
23

Relative lowering of vapour pressure of a dilute solution of glucose dissolved in $$1 \mathrm{~kg}$$ of water is 0.002 . The molality of the solution is

KCET 2019
24
Which of the following aqueous solutions should have the highest boiling point?
KCET 2018
25
Isotonic solutions are solutions having the same
KCET 2018
26
The, vant Hoff's factor ' $\boldsymbol{i}$ ' accounts for
KCET 2017
27
When the pure solvent diffuses out of the solution through the semi-permeable membrane then the process is called
KCET 2017
28
Which of the following aqueous solution has highest freezing point?
KCET 2017
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