Liquid Solution · Chemistry · KCET

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MCQ (Single Correct Answer)

1
The relative lowering of vapour pressure produced by dissolving $18$ g of urea (Molar mass $= 60\text{ g mol}^{-1}$) in $100$ g of water is
KCET 2026
2
When $0.0106$ mole of acetic acid was dissolved in $1$ kg of water, the freezing point depression for this strength of acid was $0.0205$ K. If the calculated freezing point depression is $0.0197$ K, Van't Hoff factor (i) and degree of dissociation of acetic acid respectively are
KCET 2026
3
Match List-I (Laws) with the List-II (Mathematical expressions):
List-IList-II
(a)Henry's law(i)$p_1 = p_1^0 x_1$
(b)Raoult's law(ii)$p = K_H \chi$
(c)First law of thermodynamics(iii)$\Lambda_m = v_+ \lambda_+ + v_- \lambda_-$
(d)Kohlrausch's law(iv)$\Delta U = q + w$
Codes:
KCET 2026
4
Which of the following is CORRECT with respect to the property mentioned against it?
KCET 2026
5

Among the following 0.1 m aqueous solutions, which one will exhibit the lowest boiling point elevation, assuming complete ionization of the compound in solution?

KCET 2025
6

Variation of solubility with temperature t for a gas in liquid is shown by the following graphs. The correct representation is

KCET 2025
7

180 g of glucose, $\mathrm{C}_6 \mathrm{H}_{12} \mathrm{O}_6$, is dissolved in 1 kg of water in a vessel. The temperature at which water boils at 1.013 bar is _________ (given, $\mathrm{K}_{\mathrm{b}}$ for water is $052 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$. Boiling point for pure water is 373.15 K )

KCET 2025
8

If $N_2$ gas is bubbled through water at 293 K , how many moles of $N_2$ gas would dissolve in 1 litre of water? Assume that $\mathrm{N}_2$ exerts a partial pressure of 0.987 bar.

[Given $\mathrm{K}_{\mathrm{H}}$ for $\mathrm{N}_2$ at 293 K is 76.48 K bar ]

KCET 2025
9

Vapour pressure of a solution containing 18 g of glucose and 178.2 g of water at $100^{\circ} \mathrm{C}$ is (Vapour pressure of pure water at $100^{\circ} \mathrm{C}=760$ torr)

KCET 2024
10

A mixture of phenol and aniline shows negative deviation from Raoult's law. This is due to the formation of

KCET 2024
11

Which one of the following pairs will show positive deviation from Raoult's law?

KCET 2024
12

For which one of the following mixtures is composition uniform throughout?

KCET 2024
13

The swelling in feet and ankles of an aged person due to sitting continuously for long hours during travel, is reduced by soaking the feet in warm salt water. This is because of

KCET 2023
14

A sample of water is found to contain $$5.85 \%$$ $$\left(\frac{w}{w}\right)$$ of $$A B$$ (molecular mass 58.5 ) and $$9.50 \%$$ $$\left(\frac{w}{w}\right) X Y_2$$ (molecular mass 95). Assuming $$80 \%$$ ionisation of $$A B$$ and $$60 \%$$ ionisation of $$X Y_2$$, the freezing point of water sample is [Given, $$K_f$$ for water $$1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$$, Freezing point of pure water is $$273 \mathrm{~K}$$ and $$A, B$$ and $$Y$$ are monovalent ions.]

KCET 2023
15

Solubility of a gas in a liquid increases with

KCET 2022
16

The rise in boiling point of a solution containing $$1.8 \mathrm{~g}$$ of glucose in $$100 \mathrm{~g}$$ of solvent is $$0.1^{\circ} \mathrm{C}$$. The molal elevation constant of the liquid is

KCET 2022
17

If $$3 \mathrm{~g}$$ of glucose (molar mass $$=180 \mathrm{~g}$$) is dissolved in $$60 \mathrm{~g}$$ of water at $$15^{\circ} \mathrm{C}$$, the osmotic pressure of the solution will be

KCET 2022
18

Which of the following colligative properties can provide molar mass of proteins, polymers and colloids with greater precision?

KCET 2022
19

Henry's law constant for the solubility of $$\mathrm{N}_2$$ gas in water at $$298 \mathrm{~K}$$ is $$1.0 \times 10^5 \mathrm{~atm}$$. The mole fraction of $$\mathrm{N}_2$$ in air is 0.8 . The number of moles of $$\mathrm{N}_2$$ from air dissolved in 10 moles of water at $$298 \mathrm{~K}$$ and $$5 \mathrm{~atm}$$ pressure is

KCET 2021
20

Choose the correct statement.

KCET 2021
21

The $$K_{\mathrm{H}}$$ value ($$\mathrm{K}$$ bar) of argon (I), carbondioxide (II), formaldehyde (III) and methane (IV) are respectively $$40.3,167, 1.83 \times 0^{-5}$$ and 0.413 at $$298 \mathrm{~K}$$. The increasing order of solubility of gas in liquid is

KCET 2021
22

The vapour pressure of pure liquids $$A$$ and $$B$$ are 450 and $$700 \mathrm{~mm}$$ of $$\mathrm{Hg}$$ at $$350 \mathrm{~K}$$ respectively. If the total vapour pressure of the mixture is $$600 \mathrm{~mm}$$ of $$\mathrm{Hg}$$, the composition of the mixture in the solution is

KCET 2021
23

Which of the following pair of solutions is isotonic?

KCET 2020
24

Solute '$$X$$' dimerises in water to the extent of $$80\%$$. 2.5g of '$$X$$' in $$100 \mathrm{~g}$$ of water increases the boiling point by $$0.3^{\circ} \mathrm{C}$$. The molar mass of 'X' is $$[K_b=0.52 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}]$$

KCET 2020
25

A non-volatile solute, '$$A$$' tetramerises in water to the extent of $$80 \%.$$ $$2 .5 \mathrm{~g}$$ of '$$A$$' in $$100 \mathrm{~g}$$ of water, lower the freezing point by $$0.3^{\circ} \mathrm{C}$$. The molar mass of '$$A$$' in $$\mathrm{g}$$ is $$\left(K_f\right.$$ for water $$=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1})$$

KCET 2019
26

Solution '$$A$$' contains acetone dissolved in chloroform and solution '$$B$$' contains acetone dissolved in carbon disulphide. The type of deviations from Raoult's law shown by solutions $$A$$ and $$B$$, respectively are

KCET 2019
27

Relative lowering of vapour pressure of a dilute solution of glucose dissolved in $$1 \mathrm{~kg}$$ of water is 0.002 . The molality of the solution is

KCET 2019
28
Which of the following aqueous solutions should have the highest boiling point?
KCET 2018
29
Isotonic solutions are solutions having the same
KCET 2018
30
The, vant Hoff's factor ' $\boldsymbol{i}$ ' accounts for
KCET 2017
31
When the pure solvent diffuses out of the solution through the semi-permeable membrane then the process is called
KCET 2017
32
Which of the following aqueous solution has highest freezing point?
KCET 2017