1
TS EAMCET 2023 (Online) 14th May Evening Shift
MCQ (Single Correct Answer)
+1
-0

In the structure of a solid, W atoms are located at the cube corners of the unit cell, O atoms are located at the cube edges and Na atoms at the cube centres. The formula of the compound is

A

$\mathrm{NaWO}_3$

B

$\mathrm{NaWO}_2$

C

$\mathrm{Na}_2 \mathrm{~W}_2 \mathrm{O}_2$

D

$\mathrm{Na}_2 \mathrm{WO}_3$

2
TS EAMCET 2023 (Online) 14th May Evening Shift
MCQ (Single Correct Answer)
+1
-0

An aqueous solution of a non-volatile solute boils at $100.17^{\circ} \mathrm{C}$. The temperature at which this solution will freeze (in ${ }^{\circ} \mathrm{C}$ ) is

$$ \begin{aligned} & \left(K_b\left(\mathrm{H}_2 \mathrm{O}\right)=0.512^{\circ} \mathrm{C} \mathrm{~kg} \mathrm{~mol}^{-1},\right. \\ & \left.K_f\left(\mathrm{H}_2 \mathrm{O}\right)=1.86^{\circ} \mathrm{C} \mathrm{~kg} \mathrm{~mol}^{-1}\right) \end{aligned} $$

A

-0.62

B

-0.512

C

-1.24

D

-1.86

3
TS EAMCET 2023 (Online) 14th May Evening Shift
MCQ (Single Correct Answer)
+1
-0

A possible mechanism for the gaseous reaction $2 \mathrm{H}_2+2 \mathrm{NO} \longrightarrow 2 \mathrm{H}_2 \mathrm{O}+\mathrm{N}_2$ is

Step 1:2 $\mathrm{NO} \rightleftharpoons \mathrm{N}_2 \mathrm{O}_2$

Step 2 : $\mathrm{N}_2 \mathrm{O}_2+\mathrm{H}_2 \longrightarrow \mathrm{~N}_2 \mathrm{O}+\mathrm{H}_2 \mathrm{O}$ (slow)

Step 3: $\mathrm{N}_2 \mathrm{O}+\mathrm{H}_2 \longrightarrow \mathrm{~N}_2+\mathrm{H}_2 \mathrm{O}$

The rate law for this reaction is

A

$R=k[\mathrm{NO}]^2\left[\mathrm{H}_2\right]^2$

B

$R=k[\mathrm{NO}]\left[\mathrm{H}_2\right]^2$

C

$R=k[\mathrm{NO}]^{1 / 2}\left[\mathrm{H}_2\right]$

D

$R=k[\mathrm{NO}]^2\left[\mathrm{H}_2\right]$

4
TS EAMCET 2023 (Online) 14th May Evening Shift
MCQ (Single Correct Answer)
+1
-0

The reduction potential of a half-cell consisting of a Pt electrode immersed in $2.0 \mathrm{M} \mathrm{Fe}^{2+}$ and $0.02 \mathrm{M} \mathrm{Fe}^{3+}$ solution (in V) is

Given : $\left(\frac{2.303 R T}{F}=0.059, E_{\mathrm{Fe}^{3+} \mid \mathrm{Fe}^{2+}}^{\circ}=0.771 \mathrm{~V}\right)$

A

0.543

B

0.653

C

0.733

D

0.822

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