Given,
$$ \mathrm{H}_2(g)+\frac{1}{2} \mathrm{O}_2(g) \longrightarrow \mathrm{H}_2 \mathrm{O}(l) ; \Delta H=-285 \mathrm{~kJ} $$
$$ \begin{aligned} & \mathrm{N}_2 \mathrm{O}_5(g)+\mathrm{H}_2 \mathrm{O}(l) \longrightarrow 2 \mathrm{HNO}_3(l) ; \Delta H=-76.6 \mathrm{~kJ} \\ & \mathrm{~N}_2(g)+3 \mathrm{O}_2(g)+\mathrm{H}_2(g) \longrightarrow 2 \mathrm{HNO}_3(l) ; \\ & \Delta H=-348.2 \mathrm{~kJ} \end{aligned} $$
Calculate the $\Delta \mathrm{H}$ of $2 \mathrm{~N}_2(\mathrm{~g})+5 \mathrm{O}_2(\mathrm{~g}) \longrightarrow 2 \mathrm{~N}_2 \mathrm{O}_5(\mathrm{~g})$.
In which of the following reactions at equilibria, the position of the equilibrium shifts towards the products, if the total pressure is increased?
(i) $X_2(g)+3 Y_2(g) \rightleftharpoons 2 X_3(g)$
(ii) $X_2(g)+Y_2(g) \rightleftharpoons 2 X Y(g)$
(iii) $X_2(g)+Z_2(g) \rightleftharpoons 2 X Z(g)$
(iv) $X_2(g)+Y_4(g) \rightleftharpoons 2 X Y_2(g)$
Phosphorus and phosphoric acids are, respectively,
............... acids.
The freezing point of heavy water at 1 atm pressure is
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