$$ \text { Match the following with their } \mathrm{pKa} \text { values } $$

$$ A \text { and } B \text { respectively are } $$

8.8 g of monohydric alcohol added to ethyl magnesium iodide in ether liberates $2240 \mathrm{~cm}^3$ of ethane at STP. This monohydric alcohol when oxidised using pyridinium-chloro-chromate, forms a carbonyl compound that answers silver mirror test (Tollen's test). The monohydric alcohol is

When a tertiary alcohol ' $A^{\prime}\left(\mathrm{C}_4 \mathrm{H}_{10} \mathrm{O}\right)$ reacts with $20 \% \mathrm{H}_3 \mathrm{PO}_4$ at 358 K , it gives a compound ' $B^{\prime}\left(\mathrm{C}_4 \mathrm{H}_8\right)$ as a major product. The IUPAC name of the compound ' $B$ ' is