1
KCET 2023
MCQ (Single Correct Answer)
+1
-0

The resistance of $$0.1 \mathrm{~M}$$ weak acid $$\mathrm{H} A$$ in a conductivity cell is $$2 \times 10^3 \mathrm{~Ohm}$$. The cell constant of the cell is $$0.78 ~\mathrm{C} \mathrm{~m}^{-1}$$ and $$\lambda_{\mathrm{m}}^{\circ}$$ of acid $$\mathrm{H} A$$ is $$390 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$$. The $$\mathrm{pH}$$ of the solution is

A
3.3
B
4.2
C
5
D
3
2
KCET 2023
MCQ (Single Correct Answer)
+1
-0

In which one of the following reactions, rate constant has the unit $$\mathrm{mol} \mathrm{~L}^{-1} \mathrm{~s}^{-1}$$ ?

A
Acid catalysed hydrolysis of $$\mathrm{CH}_3 \mathrm{COOCH}_3$$
B
$$\mathrm{CHCl}_3+\mathrm{Cl}_2 \longrightarrow \mathrm{CCl}_4+\mathrm{HCl}$$
C
$$2 \mathrm{NO}(g)+\mathrm{O}_2(g) \longrightarrow 2 \mathrm{NO}_2(g)$$
D
Decomposition of HI on the surface of gold
3
KCET 2023
MCQ (Single Correct Answer)
+1
-0

For a reaction, the value of rate constant at $$300 \mathrm{~K}$$ is $$6.0 \times 10^5 \mathrm{~s}^{-1}$$. The value of Arrhenius factor $$A$$ at infinitely high temperature is

A
$$6 \times 10^5 \times e^{-E_a / 300 R}$$
B
$$e^{-E_a / 300 R}$$
C
$$\frac{6 \times 10^{-5}}{300}$$
D
$$6 \times 10^5$$
4
KCET 2023
MCQ (Single Correct Answer)
+1
-0

The rate constant $$k_1$$ and $$k_2$$ for two different reactions are $$10^{16} \times e^{-2000 / T}$$ and $$10^{15} \times e^{-1000 / T}$$ respectively. The temperature at which $$k_1=k_2$$ is

A
$$\frac{2000}{2.303} \mathrm{~K}$$
B
$$2000 \mathrm{~K}$$
C
$$\frac{1000}{2.303} \mathrm{~K}$$
D
$$1000 \mathrm{~K}$$
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