1
KCET 2023
MCQ (Single Correct Answer)
+1
-0

If a didentate ligand ethane-1, 2-diamine is progressively added in the molar ratio en : Ni :: 1: 1, 2 : 1, 3 : 1 to $$\left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+}$$ aq solution, following co-ordination entities are formed.

I. $$\left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_4 \mathrm{en}\right]^{2+}(a q)$$ - pale blue

II. $$\left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_2(\mathrm{en})_2\right]^{2+}(\mathrm{aq})$$ - blue/purple

III. $$\left[\mathrm{Ni}(\mathrm{en})_3\right]^{2+}(\mathrm{aq})$$ - violet

The wavelength in $$\mathrm{nm}$$ of light absorbed in case of I and III are respectively

A
$$475 \mathrm{~nm}$$ and $$310 \mathrm{~nm}$$
B
$$300 \mathrm{~nm}$$ and $$475 \mathrm{~nm}$$
C
$$310 \mathrm{~nm}$$ and $$500 \mathrm{~nm}$$
D
$$600 \mathrm{~nm}$$ and $$535 \mathrm{~nm}$$
2
KCET 2023
MCQ (Single Correct Answer)
+1
-0

Which of the following is an organometallic compound

A
$$\mathrm{CH}_3 \mathrm{COONa}$$
B
$$\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{MgBr}$$
C
$$\left(\mathrm{CH}_3 \mathrm{COO}\right)_2 \mathrm{Ca}$$
D
$$\mathrm{CH}_3 \mathrm{ONa}$$
3
KCET 2023
MCQ (Single Correct Answer)
+1
-0

A better reagent to oxidise primary alcohols into aldehyde is

A
PCC
B
Alkaline $$\mathrm{KMnO}_4$$
C
Acidified $$\mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7$$
D
$$\mathrm{CrO}_3$$
4
KCET 2023
MCQ (Single Correct Answer)
+1
-0

In the reaction,

$${C_6}{H_5}CN\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{(ii)\,{H_3}{O^ + }}^{(i)\,SnC{l_2} + HCl}} X\mathrel{\mathop{\kern0pt\longrightarrow} \limits_{}^{conc.\,KOH}} Y + Z$$

Formation of $$X, Y$$ and $$Z$$ are known by

A
Rosenmund reduction, Cannizzaro reaction
B
Clemmensen reduction, Sandmeyer reaction
C
Wolff-Kishner reaction, Wurtz reaction
D
Stephen reaction, Canizzaro reaction
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