$$ \text { Match the Coordination compounds in Column I with the type of stereoisomerism given in Column II exhibited by them. } $$
| $$ \text { Column I } $$ |
$$ \text { Column I } $$ |
||
|---|---|---|---|
| A | $$ \left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right] $$ |
P | fac-mer |
| B | $$ \mathrm{Ni}\left[\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right] $$ |
Q | cis -trans |
| C | $$ \left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3\left(\mathrm{NO}_2\right)_3\right] $$ |
R | only cis isomer shows optical isomerism |
| D | $$ \left[\mathrm{Pt} \mathrm{Cl}_2(\mathrm{en})_2\right]^{2+} $$ |
S | does not exhibit isomerism. |
$$ A-S \quad B-R \quad C-Q \quad D-P $$
$$ A-S \quad B-P \quad C-Q \quad D-R $$
$$ A-Q \quad B-S \quad C-O \quad D-R $$
$$ A-R \quad B-P \quad C-S \quad D-Q $$
Identify the correct mathematical expression which represents the variation in molar conductivity of a weak acid having concentration C and ionisation constant $\mathrm{K}_{\mathrm{a}}$
( $\lambda_m^{\infty}=$ molar conductivity at infinite dilution, $\lambda_{\mathrm{m}}=$ molar conductivity at concentration C )
$K_a=\lambda_m^2 C / \lambda_m^{\infty}\left(\lambda_m^{\infty}-\lambda_m\right)$
$K_a=\lambda_m \lambda_m^{\infty}-\left(\lambda_m^{\infty}\right)^2+\lambda_m^2 C$
$\lambda_m+\lambda_m^{\infty}+K_a C^{\frac{1}{2}}=0$
$K_a=\lambda_m^2 C / \lambda_m^{\infty}\left(\lambda_m^{\infty}+\lambda_m\right)$
Lassaigne's test for the detection of nitrogen fails in
$\mathrm{NH}_2-\mathrm{NH}_2 \mathrm{HCl}$
$\mathrm{NH}_2 \mathrm{CONHNH}_2 \mathrm{HCl}$
$\mathrm{C}_6 \mathrm{H}_5 \mathrm{NHNH}_2 \mathrm{HCl}$
$\mathrm{NH}_2 \mathrm{CONH}_2$
$\Delta \mathrm{H}$ and $\Delta \mathrm{S}$ for a reaction are $35.5 \mathrm{~kJ} \mathrm{~mol}^{-1}$ and $83.6 \mathrm{~J} \mathrm{~K}^{-1}$ respectively. Assuming that $\Delta \mathrm{H}$ and $\Delta \mathrm{S}$ do not vary with temperature, the reaction is spontaneous when:
$\mathrm{T}<425 \mathrm{~K}$
$\mathrm{T}<350 \mathrm{~K}$
$\mathrm{T}>425 \mathrm{~K}$
$T>298 \mathrm{~K}$
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