Which of the following is the correct reaction of Hinsberg's reagent with primary, secondary and tertiary amines?
Primary amine forms N , N -dialkyl Benzene sulphonamide which is soluble in alkali
Tertiary amine forms N, N-dialkyl Benzene sulphonamide which is insoluble in alkali
Secondary amine forms N, N-dialkyl Benzene sulphonamide which is soluble in alkali
Primary amine forms N -alkyl Benzene sulphonamide which is soluble in alkali
The Bohr orbit of the hydrogen atom ( $n=1$ ) is $0.530 \mathop {\rm{A}}\limits^{\rm{o}} $. The radius of the first excited state orbit in $\mathop {\rm{A}}\limits^{\rm{o}} $ is:
0.16
5.21
1.66
2.12
Which of the following is NOT TRUE about nucleophilic addition reactions of aldehydes?
2,4 DNP derivatives are useful to identify aldehydes and ketones
Hemiacetals are gem-dialkoxy compounds
The hydrogensulphite addition product is useful for separation and purification of aldehydes
Aldehydes and ketones react very slowly with pure HCN to yield cyanohydrins
$$ \text { The solution of } \boldsymbol{d} \boldsymbol{y}=\boldsymbol{\operatorname { c o s }} \boldsymbol{x}(\mathbf{2}-\boldsymbol{y} \boldsymbol{\operatorname { c o s e c }} \boldsymbol{x}) \boldsymbol{d} \boldsymbol{x} \quad \text { where } y=\sqrt{2} \text { when } x=\frac{\boldsymbol{\pi}}{4} \text { is } $$
$y=\sin x+\frac{1}{2} \operatorname{cosec} x$
$y=\tan \left(\frac{x}{2}\right)+\cot \left(\frac{x}{2}\right)$
$y \sin x=\frac{1}{2} \cos 2 x$
$y=\frac{1}{\sqrt{2}} \sec x+\sqrt{2} \cos \left(\frac{x}{2}\right)$
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