The rate constants for two different reactions, $\mathrm{k}_1$ and $\mathrm{k}_2$ are $10^{16} \cdot \mathrm{e}^{-2000 / \mathrm{T}}$ and $10^{15} \cdot \mathrm{e}^{-1000 / \mathrm{T}}$ respectively. The temperature at which $k_1=k_2$ is
$1000 K$
$\frac{2000}{2.303} K$
$\frac{1000}{2.303} K$
$2000 K$
The hybridisation of atomic orbitals of nitrogen in $\mathrm{NO}_2{ }^{+}, \mathrm{NO}_3{ }^{-}$and $\mathrm{NH}_4{ }^{+}$are respectively
$s p, s p^2, s p^3$
$s p, s p^3, s p^2$
$s p^2, s p^2, s p^3$
$s p^2, s p, s p^3$
An aliphatic compound $[\mathrm{X}]$, Molecular formula $\left(\mathrm{C}_4 \mathrm{H}_{10} \mathrm{O}\right)$ can be prepared from Acetone and $\mathrm{R}-\mathrm{Mg}-\mathrm{X}$.
$[\mathrm{X}]$ with $20 \%$ Phosphoric acid gives an unsaturated compound $\mathrm{C}_4 \mathrm{H}_8[\mathrm{Y}]$. Compound $[\mathrm{Y}]$ is also obtained on heating $[\mathrm{X}]$ with Copper metal at 573 K . $[\mathrm{X}]$ shows no reaction with PCC but on heating with acidified $\mathrm{KMnO}_4$ it forms Acetone $+\mathrm{CO}_2+\mathrm{H}_2 \mathrm{O}$.
Compounds $[\mathrm{X}]$ and $[\mathrm{Y}]$ are $\_\_\_\_$ and $\_\_\_\_$
[X]: Butan-2-ol [Y]: But-2-ene
[X]: 2-Methylpropan-1-ol [Y]: But-1-ene
[X]: 2-Methylpropan-2-ol [Y]: 2-Methylpropene
[X]: Butan-1-ol [Y]: But-1-ene
Rate law can be determined from a balanced chemical equation if
one of the reactants is in excess
there is a sequence of elementary reactions
it is a reversible reaction
it is an elementary reaction
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