The number of atoms in $$2.4 \mathrm{~g}$$ of body centred cubic crystal with edge length $$200 \mathrm{pm}$$ is (density $$=10 \mathrm{~g} \mathrm{~cm}^{-3}, \mathrm{~N}_A=6 \times 10^{23}$$ atoms$$/ \mathrm{mol}$$)
1 mole of $$\mathrm{NaCl}$$ is doped with $$10^{-5}$$ mole of $$\mathrm{SrCl}_2$$. The number of cationic vacancies in the crystal lattice will be
A non-volatile solute, '$$A$$' tetramerises in water to the extent of $$80 \%.$$ $$2 .5 \mathrm{~g}$$ of '$$A$$' in $$100 \mathrm{~g}$$ of water, lower the freezing point by $$0.3^{\circ} \mathrm{C}$$. The molar mass of '$$A$$' in $$\mathrm{g}$$ is $$\left(K_f\right.$$ for water $$=1.86 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1})$$
Solution '$$A$$' contains acetone dissolved in chloroform and solution '$$B$$' contains acetone dissolved in carbon disulphide. The type of deviations from Raoult's law shown by solutions $$A$$ and $$B$$, respectively are