1
COMEDK 2025 Morning Shift
MCQ (Single Correct Answer)
+1
-0
What is the reduction potential of a half-cell consisting of a Pt electrode dipped in $2.2 \mathrm{M} \mathrm{Fe}^{2+}$ and $0.04 \mathrm{M} \mathrm{Fe}^{3+}$ solution where the reaction taking place is conversion of $\mathrm{Fe}^{3+}$ ions to $\mathrm{Fe}^{2+}$ ?

$$\mathrm{E}^0\left(\mathrm{Fe}^{3+} / \mathrm{Fe}^{2+}\right)=0.771 \mathrm{~V}$$

A
0.598 V
B
0.723 V
C
0.668 V
D
0.719 V
2
COMEDK 2025 Morning Shift
MCQ (Single Correct Answer)
+1
-0

Both reactions (i) and (ii) give the same compound X as the major product. Identify X

(i). 3-Methylbut-1-ene $+\mathrm{HCl} \rightarrow \mathrm{X}$

(ii). Neopentyl alcohol $+\mathrm{HCl}\left(\right.$ anh. $\left.\mathrm{ZnCl}_2\right) \rightarrow \mathrm{X}$

A
$\left(\mathrm{CH}_3\right)_2-\mathrm{CH}-\mathrm{CHCl}-\mathrm{CH}_3$
B
$\left(\mathrm{CH}_3\right)_2-\mathrm{CCl}-\mathrm{CH}_2-\mathrm{CH}_3$
C
$\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{CH}\left(\mathrm{CH}_3\right)-\mathrm{CH}_2 \mathrm{Cl}$
D
$\left(\mathrm{CH}_3\right)_2-\mathrm{CH}-\mathrm{CH}_2-\mathrm{CH}_2 \mathrm{Cl}$
3
COMEDK 2025 Morning Shift
MCQ (Single Correct Answer)
+1
-0
Two chemical reactions of the same order have equal Frequency factor value. Their Activation energies differ by $26.8 \mathrm{~kJ} / \mathrm{mol}$. At 300 K if $k_2=x k_1$ find the value of $x$.
A
$4.631 \times 10^4$
B
$1.143 \times 10^3$
C
$2.286 \times 10^3$
D
4.665
4
COMEDK 2025 Morning Shift
MCQ (Single Correct Answer)
+1
-0

Arrange the following compounds in the decreasing order of the molar conductivities of their aqueous solutions.

A B C D
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{Cl}_2$ $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3 \mathrm{Cl}_3\right]$ $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right] \mathrm{Cl}$ $\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right] \mathrm{Cl}_3$

A
$\mathrm{B}>\mathrm{C}>\mathrm{A}>\mathrm{D}$
B
$\mathrm{D}>\mathrm{A}>\mathrm{C}>\mathrm{B}$
C
$\mathrm{B}>\mathrm{A}>\mathrm{C}>\mathrm{D}$
D
$\mathrm{A}>\mathrm{B}>\mathrm{D}>\mathrm{C}$
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