The sets of molecules in which central atom has no lone pair of electrons are

I. $\mathrm{SnCl}_2, \mathrm{NH}_3, \mathrm{SF}_4$

II. $\mathrm{HgCl}_2, \mathrm{SO}_3, \mathrm{SF}_6$

III. $\mathrm{BeCl}_2 \mathrm{BF}_3, \mathrm{PCl}_5$

IV. $\mathrm{ClF}_3, \mathrm{BrF}_5, \mathrm{XeF}_6$

The isobars of one mole of an ideal gas were obtained at three different pressure ( $p_1, p_2$ and $p_3$ ). The slopes of these isobars are $m_1, m_2$ and $m_3$ respectively. If $p_1 < p_2 < p_3$, then the correct relation of the slopes is

100 mL of $0.05 \mathrm{M} \mathrm{Cu}^{2+}$ aqueous solution is added to IL of 0.1 M KI solution. The number of moles of $\mathrm{I}_2$ and $\mathrm{Cu}_2 \mathrm{I}_2$ formed are respectively.

The $C_p$ of an ideal gas is $10314 \mathrm{Jmol}^{-1} \mathrm{~K}^{-1}$. One mole of this gas is expanded against a constant pressure of $p \mathrm{~atm}$. The change in temperature during expansion is 1.0 K . The value of $q$ (in J ) and $\Delta H$ (in $\mathrm{Jmol}^{-1}$ ) are respectively.