Find the average rate of formation of $$\mathrm{NO}_{2(\mathrm{~g})}$$, in following reaction.
$$\begin{aligned} & 2 \mathrm{~N}_2 \mathrm{O}_{5(\mathrm{~g})} \rightarrow 4 \mathrm{NO}_{2(\mathrm{~g})}+\mathrm{O}_{2(\mathrm{~g})} \\ & {\left[-\frac{\Delta\left[\mathrm{N}_2 \mathrm{O}_5\right]}{\Delta \mathrm{t}}\right]=x \mathrm{~mol} \mathrm{~dm}^{-3} \mathrm{~s}^{-1}} \end{aligned}$$
Calculate the rate constant for the first order reaction, $$\mathrm{A} \rightarrow \mathrm{B}$$ if the rate of reaction is $$5.4 \times 10^{-6} \mathrm{~mol} \mathrm{~dm}^{-3} \mathrm{~s}^{-1}$$ and $$[\mathrm{A}]=0.3 \mathrm{M}$$.
Identify the product obtained when benzonitrile is reduced by stannous chloride in presence of hydrochloric acid followed by acid hydrolysis.
Find solubility in terms of $$\mathrm{mol} \mathrm{~L}^{-1}$$ if solubility product of silver bromide is $$6.4 \times 10^{-13}$$.