The system that forms maximum boiling azeotrope is:
Benzene-toluene
Carbon-di-sulphide-acetone
Ethyl alcohol-water
Acetone-chloroform
A Nitrogen containing organic compound with molecular formula $\mathrm{C}_3 \mathrm{H}_5 \mathrm{~N}$ undergoes the following reactions.
$$ \begin{aligned} & \mathrm{C}_3 \mathrm{H}_5 \mathrm{~N}+\mathrm{Na} / \mathrm{Hg} \text { in } \mathrm{C}_2 \mathrm{H}_5 \mathrm{OH} \rightarrow[\mathrm{~A}] \\ & {[\mathrm{A}]+\mathrm{CH}_3 \mathrm{COCl} / \mathrm{NaOH}(\mathrm{aq}) \rightarrow[\mathrm{B}]} \\ & {[\mathrm{A}]+\mathrm{CHCl}_3 / \mathrm{KOH} \text { on heating } \rightarrow[\mathrm{C}] \text { (foul smelling compound) }} \end{aligned} $$
Identify compounds $[\mathrm{B}]$ and $[\mathrm{C}]$
[B]: $\left(\mathrm{CH}_3\right)_3-\mathrm{C}-\mathrm{NH}-\mathrm{COCl}$ [C]: $\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{CN}$
$[\mathrm{B}]: \mathrm{CH}_3-\mathrm{CH}_2-\mathrm{NH}-\mathrm{COCH}_2-\mathrm{CH}_3$ [C]: $\mathrm{CH}_3-\left(\mathrm{CH}_2\right)_2-\mathrm{CN}$
$[\mathrm{B}]: \mathrm{CH}_3-\left(\mathrm{CH}_2\right)_2-\mathrm{NH}-\mathrm{COCH}_3$ [C]: $\mathrm{CH}_3-\left(\mathrm{CH}_2\right)_2-\mathrm{NC}$
$[\mathrm{B}]:\left(\mathrm{CH}_3\right)_2-\mathrm{CH}-\mathrm{NH}-\mathrm{COCH}_3$ [C]: $\mathrm{CH}_3-\mathrm{CH}_2-\mathrm{NC}$
Choose the incorrect statement.
Propan-2-amine can be obtained by reacting acetoxime with $\mathrm{Na} / \mathrm{C}_2 \mathrm{H}_5 \mathrm{OH}$
Aniline cannot be prepared by Phthalimide reaction
The decreasing order of basic strength of amines in aqueous solution is Ethanamine > $\mathrm{N}, \mathrm{N}$-Dimethylaniline > Benzenamine
Fluorobenzene cannot be prepared from Benzenediazonium chloride by Sandmeyer's reaction because Fluorination of the Diazonium salt is highly endothermic in nature
The quantity of Ca that can be produced from molten $\mathrm{CaCl}_2$, with the same quantity of electricity (in coulombs) required to produce 4.8 g of Mg from molten $\mathrm{MgCl}_2$ is: [Atomic mass of $\mathrm{Mg}=24 \mathrm{u}$; Atomic mass of $\mathrm{Ca}=40 \mathrm{u}$ ]
5.2 g
6.0 g
8.0 g
4.8 g
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