The $\Delta \mathrm{G}^{\circ}$ for the reaction, $C d^{2+}(a q)+Z n(s) \rightarrow Z n^{2+}(a q)+C d(s)$ is:
$\left[E_{C d^{2+} / C d}^o=-0.403, E_{Z n^{2+} / Z n}^o=-0.763 \mathrm{~V}\right]$$-69.5 k J$
$-72.2 kJ$
$-44.5 kJ$
$-50 kJ$
$$ \text { Identify the correct structure of o-ethyl anisole. } $$




$$ \text { Identify the reagents, }[A] \text { and }[B] \text { used up when Salicylic acid undergoes the following reactions: } $$

A: $\frac{\left(\mathrm{CH}_3 \mathrm{CO}\right)_2 \mathrm{O}}{\mathrm{H}^{+}}$ $\mathrm{B}: \frac{\mathrm{CH}_3 \mathrm{CHO}}{\mathrm{H}^{+}}$
A: $\frac{\mathrm{CH}_3 \mathrm{COO}^{-}}{\mathrm{OH}^{-}}$ B: $\frac{\mathrm{CH}_3 \mathrm{Cl}}{\text { (warm) }}$
$\mathrm{A}: \frac{\mathrm{CH}_3 \mathrm{OH}}{\mathrm{H}^{+}}$ B: $\frac{\left(\mathrm{CH}_3 \mathrm{CO}\right)_2 \mathrm{O}}{\mathrm{H}^{+}(\text {warm })}$
$$ \mathrm{A}=\frac{\mathrm{CH}_3 \mathrm{COCl}}{(\text { warm })} \quad \mathrm{B}=\frac{\mathrm{CH}_3 \mathrm{Br}}{(\text { warm })} $$
Which of the following is an INCORRECT statement?
$\mathrm{CH}_3 \mathrm{OH}$ and $\mathrm{CH}_3 \mathrm{COCH}_3$ are separated by fractional distillation
In sodium nitroprusside test for Sulphur, the violet colour is due to formation of complex $\mathrm{Na}_4\left[\mathrm{Fe}(\mathrm{CN})_5 \mathrm{NOS}\right]$
$\mathrm{CH}_3 \mathrm{COO}^{-}, \mathrm{CN}^{-}, \mathrm{CH}_3 \mathrm{OH}, \mathrm{CH}_3-\mathrm{O}-\mathrm{CH}_3,\left(\mathrm{CH}_3\right)_3 \mathrm{~N}$ are nucleophiles
$\mathrm{AlCl}_3, \mathrm{NH}_3, \mathrm{SO}_3, \mathrm{NO}_2^{+}, \mathrm{H}_2 \mathrm{O}$ are electrophiles
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