Assertion (A) $$\mathrm{NaCl}$$ reacts with concentrated $$\mathrm{H}_2 \mathrm{SO}_4$$ to give colourless fumes with pungent smell. But on adding $$\mathrm{MnO}_2$$ the fumes become greenish yellow.
Reason (R) $$\mathrm{MnO}_2$$ oxidises $$\mathrm{HCl}$$ to chlorine gas which is greenish yellow.
Assertion (A) $$K_p$$ can be equal to or less than or even greater than the value of $$K_C$$.
Reason (R) $$K_p=K_C(R T)^{\Delta n}$$
Relation between $$K_p$$ and $$K_C$$ depends on the change in the number of moles of gaseous reactants and products.
Assertion (A) $$\mathrm{CH}_4$$ does not react with $$\mathrm{Cl}_2$$ in dark.
Reason (R) Chlorination of $$\mathrm{CH}_4$$ takes place in sunlight.
Assertion (A) $$\mathrm{CH}_3 \mathrm{OH}$$ and $$\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{OH}$$ can be distinguished by haloform test.
Reason (R) Haloform test is given by $$2^{\circ}$$ alcohol.