Assertion (A) The molecular mass of the polymers cannot be calculated using the boiling point or freezing point method.
Reason (R) The freezing point method is used for determining the molecular mass of small molecules.
Assertion (A) $$\mathrm{NaCl}$$ reacts with concentrated $$\mathrm{H}_2 \mathrm{SO}_4$$ to give colourless fumes with pungent smell. But on adding $$\mathrm{MnO}_2$$ the fumes become greenish yellow.
Reason (R) $$\mathrm{MnO}_2$$ oxidises $$\mathrm{HCl}$$ to chlorine gas which is greenish yellow.
Assertion (A) $$K_p$$ can be equal to or less than or even greater than the value of $$K_C$$.
Reason (R) $$K_p=K_C(R T)^{\Delta n}$$
Relation between $$K_p$$ and $$K_C$$ depends on the change in the number of moles of gaseous reactants and products.
Assertion (A) $$\mathrm{CH}_4$$ does not react with $$\mathrm{Cl}_2$$ in dark.
Reason (R) Chlorination of $$\mathrm{CH}_4$$ takes place in sunlight.