1
AIIMS 2018
MCQ (Single Correct Answer)
+1
-0.33

Which of the following compound has same oxidation state of the central metal atom in the cationic and anionic part?

A
$$\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_4\right]\left[\mathrm{PtCl}_6\right]$$
B
$$\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right]\left[\mathrm{PtCl}_4\right]$$
C
$$\left[\mathrm{Pt}(\mathrm{Py})_4\right]\left[\mathrm{PtCl}_4\right]$$
D
$$\mathrm{K}_4\left[\mathrm{Ni}(\mathrm{CN})_6\right]$$
2
AIIMS 2018
MCQ (Single Correct Answer)
+1
-0.33

The rate constant for the first order decomposition of a certain reaction is described by the equation $$\ln k\left(\mathrm{~s}^{-1}\right)=14.34-\frac{1.25 \times 10^4 \mathrm{~K}}{T}$$. The energy of activation for this reaction is

A
$$1.26 \times 10^4 \mathrm{~cal} \mathrm{~mol}^{-1}$$
B
$$4.29 \times 10^4 \mathrm{~cal} \mathrm{~mol}^{-1}$$
C
$$3.12 \times 10^4 \mathrm{~cal} \mathrm{~mol}^{-1}$$
D
$$2.50 \times 10^4 \mathrm{~cal} \mathrm{~mol}^{-1}$$
3
AIIMS 2018
MCQ (Single Correct Answer)
+1
-0.33

In which of the following arrangements, the order is not strictly according to the property written against it?

A
$$\mathrm{CO}_2<\mathrm{SiO}_2<\mathrm{SnO}_2<\mathrm{PbO}_2$$ (oxidising power)
B
$$\mathrm{HF}^2<\mathrm{HCl}<\mathrm{HBr}<\mathrm{HI}$$ (acidic strength)
C
$$\mathrm{NH}_3>\mathrm{PH}_3<\mathrm{AsH}_3<\mathrm{SbH}_3$$ (basic strength)
D
$$\mathrm{B}<\mathrm{C}<\mathrm{O}<\mathrm{N}$$ (first ionisation enthalpy)
4
AIIMS 2018
MCQ (Single Correct Answer)
+1
-0.33

For a $$\mathrm{Ag}-\mathrm{Zn}$$ button cell, net reaction is

$$\begin{gathered} \mathrm{Zn}(s)+\mathrm{Ag}_2 \mathrm{O}(s) \longrightarrow \mathrm{ZnO}(s)+2 \mathrm{Ag}(s) \\ \Delta G_f^{\circ}\left(\mathrm{Ag}_2 \mathrm{O}\right)=-11.21 \mathrm{~kJ} \mathrm{~mol}^{-1} \\ \Delta G_f^{\circ}(\mathrm{ZnO})=-318.3 \mathrm{~kJ} \mathrm{~mol}^{-1} \end{gathered}$$

Then, $$E^{\circ}$$ cell of the button cell is

A
$$3.182 \mathrm{~V}$$
B
$$-1.621 \mathrm{~V}$$
C
$$1.591 \mathrm{~V}$$
D
$$-1.591 \mathrm{~V}$$
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