248 g of ethylene glycol $\left(\mathrm{C}_2 \mathrm{H}_6 \mathrm{O}_2\right)$ is added to 200 g of water to prepare antifreeze. What is the molality of resultant solution?
$$ (\mathrm{C}=12 \mathrm{u} ; \mathrm{H}=1 \mathrm{u} ; \mathrm{O}=16 \mathrm{u}) $$
A solution containing 7.5 g of urea (molar mass $=60 \mathrm{~g} \mathrm{~mol}^{-1}$ ) in 1 kg of water freezes at the same temperature as another solution containing 15 g of solute $X$, in the same amount of water. The molar mass of $X\left(\mathrm{~g} \mathrm{~mol}^{-1}\right)$ is
What is $E_{\text {cell }}$ (in V) of the following cell at $298 \mathrm{~K} ?$
$$ \begin{aligned} & \left(E_{\mathrm{Zn}^{2+} / \mathrm{Zn}}^{\ominus}=-0.76 \mathrm{~V} ; E_{\mathrm{Ni}^{2+} / \mathrm{Ni}}^{\ominus}=-0.25 \mathrm{~V} ; \frac{2.303 R T}{F}=0.06 \mathrm{~V}\right) \\ & 1(s) \mathrm{Zn}^{2+}(0.01 \mathrm{M}) \mathrm{Ni}^{2+}(0.1 \mathrm{M}) \mathrm{Ni}(s \end{aligned} $$
$A \rightarrow$ products, is a first order reaction. The following data is obtained for this reaction at $T(\mathrm{~K})$. The value of $x: y$ is
$$ \begin{array}{cc} \hline \text { Rate }\left(\mathrm{molL}^{-1} \mathrm{~min}^{-1}\right) & {[A]} \\ \hline 0.2 & 0.02 \mathrm{M} \\ \hline 0.4 & x \mathrm{M} \\ \hline 1.0 & y \mathrm{M} \\ \hline \end{array} $$
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