1
AP EAPCET 2025 - 21st May Morning Shift
MCQ (Single Correct Answer)
+1
-0

Gold crystallises in fcc lattice. The edge length of the unit cell is $4 \mathop {\rm{A}}\limits^{\rm{o}}$. The closest distance between gold atoms is ' $x$ ' $\mathop {\rm{A}}\limits^{\rm{o}}$ and density of gold is ' $y$ ' $\mathrm{g} \mathrm{cm}^{-3}$. What are $x$ and $y$ respectively?

(Molar mass of gold $=197 \mathrm{~g} \mathrm{~mol}^{-1} ; N=6 \times 10^{23} \mathrm{~mol}^{-1}$ )

A

$\sqrt{2}, 41.04$

B

$2 \sqrt{2}, 20.52$

C

$2 \sqrt{3}, 10.25$

D

$\sqrt{3}, 5.15$

2
AP EAPCET 2025 - 21st May Morning Shift
MCQ (Single Correct Answer)
+1
-0

248 g of ethylene glycol $\left(\mathrm{C}_2 \mathrm{H}_6 \mathrm{O}_2\right)$ is added to 200 g of water to prepare antifreeze. What is the molality of resultant solution?

$$ (\mathrm{C}=12 \mathrm{u} ; \mathrm{H}=1 \mathrm{u} ; \mathrm{O}=16 \mathrm{u}) $$

A

5 m

B

10 m

C

20 m

D

40 m

3
AP EAPCET 2025 - 21st May Morning Shift
MCQ (Single Correct Answer)
+1
-0

A solution containing 7.5 g of urea (molar mass $=60 \mathrm{~g} \mathrm{~mol}^{-1}$ ) in 1 kg of water freezes at the same temperature as another solution containing 15 g of solute $X$, in the same amount of water. The molar mass of $X\left(\mathrm{~g} \mathrm{~mol}^{-1}\right)$ is

A

60

B

180

C

120

D

240

4
AP EAPCET 2025 - 21st May Morning Shift
MCQ (Single Correct Answer)
+1
-0

What is $E_{\text {cell }}$ (in V) of the following cell at $298 \mathrm{~K} ?$

$$ \begin{aligned} & \left(E_{\mathrm{Zn}^{2+} / \mathrm{Zn}}^{\ominus}=-0.76 \mathrm{~V} ; E_{\mathrm{Ni}^{2+} / \mathrm{Ni}}^{\ominus}=-0.25 \mathrm{~V} ; \frac{2.303 R T}{F}=0.06 \mathrm{~V}\right) \\ & 1(s) \mathrm{Zn}^{2+}(0.01 \mathrm{M}) \mathrm{Ni}^{2+}(0.1 \mathrm{M}) \mathrm{Ni}(s \end{aligned} $$

A

0.51

B

0.48

C

0.57

D

0.54