1
AP EAPCET 2024 - 20th May Evening Shift
MCQ (Single Correct Answer)
+1
-0
The volume of an ideal gas contracts from 10.0 L to 2.0 L under an applied pressure of 2.0 atm . During contraction the system also evolved 900 J of heat. The change in internal energy (in J ) involved in the system is ( $1 \mathrm{~L} \mathrm{~atm}=101.3 \mathrm{~J}$ )
A
720.8
B
360.4
C
1620.8
D
810.4
2
AP EAPCET 2024 - 20th May Evening Shift
MCQ (Single Correct Answer)
+1
-0
The molar heat of fusion and vaporisation of benzene are 10.9 and $31.0 \mathrm{~kJ} \mathrm{~mol}^{-1}$ respectively. The changes in entropy for the solid $\rightarrow$ liquid and liquid $\rightarrow$ vapour trasitions for benzene are $x$ and $y, \mathrm{JK}^{-1} \mathrm{~mol}^{-1}$, respectively. The value of $(y-x)$ (in $\mathrm{J} \mathrm{K}^{-1} \mathrm{~mol}^{-1}$ ) is (At 1 atm benzene melts at $5.5^{\circ} \mathrm{C}$ and boils at $80^{\circ} \mathrm{C}$ )
A
87.8
B
48.7
C
39.1
D
28.7
3
AP EAPCET 2024 - 20th May Evening Shift
MCQ (Single Correct Answer)
+1
-0

At $T(\mathrm{~K})$, the equilibrium constant for the reaction $\mathrm{H}_2(g)+\mathrm{Br}_2(\mathrm{~g}) \rightleftharpoons 2 \mathrm{HBr}(\mathrm{g})$

is $1.6 \times 10^5$. If 10 bar of HBr is introduced into a sealed vessel at $T(\mathrm{~K})$, the equilibrium pressure of HBr (in bar) is approximately

A
10.20
B
10.95
C
9.95
D
11.95
4
AP EAPCET 2024 - 20th May Evening Shift
MCQ (Single Correct Answer)
+1
-0
Which of the following will make a basic buffer solution?
A
100 mL of $0.1 \mathrm{M} \mathrm{CH}_3 \mathrm{COOH}+100 \mathrm{~mL}$ of 0.1 M NaOH
B
100 mL of $0.1 \mathrm{M} \mathrm{HCl}+100 \mathrm{~mL}$ of 0.1 M NaOH
C
50 mL of $0.1 \mathrm{M} \mathrm{KOH}+25 \mathrm{~mL}$ of $0.1 \mathrm{M} \mathrm{CH}_3 \mathrm{COOH}$
D
100 mL of $0.1 \mathrm{M} \mathrm{HCl}+200 \mathrm{~mL}$ of $0.1 \mathrm{M} \mathrm{NH}_4 \mathrm{OH}$
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