Chemistry
1. For the reaction,
$$A(g)+B(g) \rightleftharpoons C(g)+D(g) ; \Delta H=Q \mathrm{~kJ}$$
The equilibrium constant cannot b2. An organic compound $$X$$ on treatment with PCC in dichloromethane gives the compound $$Y$$. Compound $$Y$$ reacts with 3. A compound $$'A' \left(\mathrm{C}_7 \mathrm{H}_8 \mathrm{O}\right)$$ is insoluble in $$\mathrm{NaHCO}_3$$ solution but d4. In set of reactions, identify $$D$$
$$\mathrm{CH}_3 \mathrm{COOH} \xrightarrow{\mathrm{SOCl}_2} A \xrightarrow[\text { A5. $$K_a$$ values for acids $$\mathrm{H}_2 \mathrm{SO}_3, \mathrm{HNO}_2, \mathrm{CH}_3 \mathrm{COOH}$$ and $$\mathrm{HCN}$6.
$$A, B$$ and $$C$$ respectively are7. The reagent which can do the conversion $$\mathrm{CH}_3 \mathrm{COOH} \longrightarrow \mathrm{CH}_3-\mathrm{CH}_2-\mathr8. $$\begin{aligned}
& \mathrm{CH}_3 \mathrm{CHO} \xrightarrow[\text { (ii) } \mathrm{H}_3 \mathrm{O}^{+}]{\text {(i) } \ma9. Which of the following is not true for oxidation?10. Which is the most suitable reagent for the following conversion?
11. $$\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{Cl} \xrightarrow{\text { Alc. } \mathrm{NH}_3} A \xrightarrow{2 \mathr12. The method by which aniline cannot be prepared is13. Permanent hardness cannot be removed by14. A hydrocarbon $$A\left(\mathrm{C}_4 \mathrm{H}_8\right)$$ on reaction with $$\mathrm{HCl}$$ gives a compound $$\mathrm{B15. RNA and DNA are chiral molecules, their chirality is due to the presence of16. The property of the alkaline earth metals that increases with their atomic number is17. Primary structure in a nucleic acid contain 3 bases as GATGC ... The chain which is complementary to this chain is18. In the detection of II group acid radical, the salt containing chloride is treated with concentrated sulphuric acid, the19. The number of six membered and five membered rings in Buckminster fullerene respectively is20. In chrysoberyl, a compound containing beryllium, aluminium and oxygen, oxide ions form cubic close packed structure. Alu21. The correct statement regarding defects in solid is22. A metal crystallises in bcc lattice with unit cell edge length of $$300 \mathrm{~pm}$$ and density $$615 \mathrm{~g~cm}^23. Henry's law constant for the solubility of $$\mathrm{N}_2$$ gas in water at $$298 \mathrm{~K}$$ is $$1.0 \times 10^5 \ma24. A pure compound contains $$2.4 \mathrm{~g}$$ of $$\mathrm{C}, 1.2 \times 10^{23}$$ atoms of $$\mathrm{H}, 0.2$$ moles of25. Choose the correct statement.26. The $$K_{\mathrm{H}}$$ value ($$\mathrm{K}$$ bar) of argon (I), carbondioxide (II), formaldehyde (III) and methane (IV) 27. The vapour pressure of pure liquids $$A$$ and $$B$$ are 450 and $$700 \mathrm{~mm}$$ of $$\mathrm{Hg}$$ at $$350 \mathrm28. Consider the following electrodes
$$\begin{aligned}
& P=\mathrm{Zn}^{2+}(0.0001 \mathrm{M}) / \mathrm{Zn}, Q=\mathrm{Zn}29. The number of angular and radial nodes in $$3 p$$ orbital respectively are30. The resistance of $$0.01 \mathrm{~m} \mathrm{~KCl}$$ solution at $$298 \mathrm{~K}$$ is $$1500 \Omega$$. If the conducti31. $$\mathrm{H}_2(g)+2 \mathrm{AgCl}(s) \rightleftharpoons 2 \mathrm{Ag}(s)+2 \mathrm{HCl}(a q)$$
$$E_{\text {cell }}^{\cir32. For a reaction, $$A+2 B \rightarrow$$ Products, when concentration of $$B$$ alone is increased half-life remains the sam33. The third ionisation enthalpy is highest in34. If the rate constant for a first order reaction is $$k$$, the time $$(t)$$ required for the completion of $$99 \%$$ of t35. The rate of a gaseous reaction is given by the expression $$k[A][B]^2$$. If the volume of vessel is reduced to one half 36. The correct IUPAC name of 37. Higher order $$(>3)$$ reactions are rare due to38. Arrange benzene, $$n$$-hexane and ethyne in decreasing order of their acidic behaviour.39. A colloidal solution is subjected to an electric field than colloidal particles more towards anode. The amount of electr40. Which of the following is an incorrect statement?41. Zeta potential is42. Which of the following compound on heating gives $$\mathrm{N}_2 \mathrm{O}$$ ?43. Which of the following property is true for the given sequence?
$$\mathrm{NH}_3>\mathrm{PH}_3>\mathrm{AsH}_3>\mathrm{SbH44. The correct order of boiling point in the following compounds is45. $$\mathrm{XeF}_6$$ on partial hydrolysis gives a compound $$X$$, which has square pyramidal geometry '$$X$$' is46. A colourless, neutral, paramagnetic oxide of nitrogen '$$P$$' on oxidation gives reddish brown gas $$Q$$. $$Q$$ on cooli47. Which of the following does not represent property stated against it?48. Which one of the following is correct for all elements from Sc to Cu?49. When the absolute temperature of ideal gas is doubled and pressure is halved, the volume of gas50. Which of the following pairs has both the ions coloured in aqueous solution? [Atomic numbers of
$$\mathrm{Sc}=21, \mathr51. For the crystal field splitting in octahedral complexes,52. Peroxide effect is observed with the addition of $$\mathrm{HBr}$$ but not with the addition of HI to unsymmetrical alken53. The IUPAC name of $$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{CO}_3\right)\right] \mathrm{Cl}$$ is
54. Homoleptic complexes among the following are
(A) $$\mathrm{K}_3\left[\mathrm{Al}\left(\mathrm{C}_2 \mathrm{O}_4\right)_355. The correct order for wavelengths of light absorbed in the complex ions $$\left[\mathrm{CoCl}\left(\mathrm{NH}_3\right)_56.
The compound A (major product) is57. Bond enthalpies of $$A_2, B_2$$ and $$A B$$ are in the ratio $$2: 1: 2$$. If bond enthalpy of formation of $$A B$$ is $$58. The order of reactivity of the compounds $$\mathrm{C}_6 \mathrm{H}_5 \mathrm{CH}_2 \mathrm{Br}, \mathrm{C}_6 \mathrm{H}_59. The major product of the following reaction is
$$\mathrm{CH}_2=\mathrm{CH}-\mathrm{CH}_2-\mathrm{OH} \xrightarrow[\text 60.
The product '$$A$$' gives white precipitate when treated with bromine water. The product '$$B$$' is treated with barium
Mathematics
1. The equation of the line joining the points $$(-3,4,11)$$ and $$(1,-2,7)$$ is2. The angle between the lines whose direction cosines are $$\left(\frac{\sqrt{3}}{4}, \frac{1}{4}, \frac{\sqrt{3}}{2}\righ3. If a plane meets the coordinate axes at $$A, B$$ and $$C$$ in such a way that the centroid of $$\triangle A B C$$ is at 4. The area of the quadrilateral $$A B C D$$ when $$A(0,4,1), B(2,3,-1), C(4,5,0)$$ and $$D(2,6,2)$$ is equal to5. The shaded region is the solution set of the inequalities
6. Given that, $$A$$ and $$B$$ are two events such that $$P(B)=\frac{3}{5}, P\left(\frac{A}{B}\right)=\frac{1}{2}$$ and $$P7. If $$A, B$$ and $$C$$ are three independent events such that $$P(A)=P(B)=P(C)=P$$, then $$P$$ (at least two of $$A, B$$ 8. Two dice are thrown. If it is known that the sum of numbers on the dice was less than 6 the probability of getting a sum9. A car manufacturing factory has two plants $$X$$ and $$Y$$. Plant $$X$$ manufactures $$70 \%$$ of cars and plant $$Y$$ m10. In a certain two $$65 \%$$ families own cell phones, 15000 families own scooter and $$15 \%$$ families own both. Taking 11. $$A$$ and $$B$$ are non-singleton sets and $$n(A \times B)=35$$. If $$B \subset A$$, then $${ }^{n(A)} C_{n(B)}$$ is equ12. Domain of $$f(x)=\frac{x}{1-|x|}$$ is13. The value of $$\cos 1200^{\circ}+\tan 1485^{\circ}$$ is14. The value of $$\tan 1^{\circ} \tan 2^{\circ} \tan 3^{\circ} \ldots \tan 89^{\circ}$$ is15. If $$\left(\frac{1+i}{1-i}\right)^x=1$$, then16. The cost and revenue functions of a product are given by $$c(x)=20 x+4000$$ and $$R(x)=60 x+2000$$ respectively, where $17. A student has to answer 10 questions, choosing at least 4 from each of the parts $$A$$ and $$B$$. If there are 6 questio18. If the middle term of the AP is 300, then the sum of its first 51 terms is19. The equation of straight line which passes through the point $$\left(a \cos ^3 \theta, a \sin ^3 \theta\right)$$ and per20. The mid points of the sides of triangle are $$(1,5,-1)(0,4,-2)$$ and $$(2,3,4)$$ then centroid of the triangle21. Consider the following statements
statement 1: $$\lim _\limits{x \rightarrow 1} \frac{a x^2+b x+c}{x^2+b x+a}$$ is 1
(wh22. If $$a$$ and $$b$$ are fixed non-zero constants, then the derivative of $$\frac{a}{x^4}-\frac{b}{x^2}+\cos x$$ is $$m a+23. The standard deviation of the numbers $$31,32,33 \ldots 46,47$$ is24. If $$P(A)=0.59, P(B)=0.30$$ and $$P(A \cap B)=0.21$$ then $$P\left(A^{\prime} \cap B^{\prime}\right)$$ is equal to25. $$f: R \rightarrow R$$ defined by $$f(x)$$ is equal to $$\left\{\begin{array}{l}2 x, x> 3 \\ x^2, 126. Let $$A=\{x: x \in R, x$$ is not a positive integer) Define $$f: A \rightarrow R$$ as $$f(x)=\frac{2 x}{x-1}$$, then $$f27. The function $$f(x)=\sqrt{3} \sin 2 x-\cos 2 x+4$$ is one-one in the interval28. Domain of the function
$$f(x)=\frac{1}{\sqrt{\left[x^2\right]-[x]-6}},$$
where $$[x]$$ is greatest integer $$\leq x$$ is29. $$\cos \left[\cot ^{-1}(-\sqrt{3})+\frac{\pi}{6}\right]$$ is equal to30. $$\tan ^{-1}\left[\frac{1}{\sqrt{3}} \sin \frac{5 \pi}{2}\right] \sin ^{-1}\left[\cos \left(\sin ^{-} \frac{\sqrt{3}}{2}31. If $$A=\left[\begin{array}{ccc}1 & -2 & 1 \\ 2 & 1 & 3\end{array}\right]$$
$$ B=\left[\begin{array}{ll}2 & 1 \\ 3 & 2 \\32. Let $$M$$ be $$2 \times 2$$ symmetric matrix with integer entries, then $$M$$ is invertible if33. If $$A$$ and $$B$$ are matrices of order 3 and $$|A|=5,|B|=3$$, then $$|3 A B|$$ is34. If $$A$$ and $$B$$ are invertible matrices then which of the following is not correct?35. If $$f(x)=\left|\begin{array}{ccc}\cos x & 1 & 0 \\ 0 & 2 \cos x & 3 \\ 0 & 1 & 2 \cos x\end{array}\right|$$, then $$\li36. If $$x^3-2 x^2-9 x+18=0$$ and $$A=\left|\begin{array}{lll}1 & 2 & 3 \\ 4 & x & 6 \\ 7 & 8 & 9\end{array}\right|$$ then t37. At $$x=1$$, the function
$$f(x)=\left\{\begin{array}{cc}
x^3-1, & 138. If $$y=\left(\cos x^2\right)^2$$, then $$\frac{d y}{d x}$$ is equal to39. For constant $$a, \frac{d}{d x}\left(x^x+x^a+a^x+a^a\right)$$ is40. Consider the following statements
Statement 1 : If $$y=\log _{10} x+\log _e x$$, then $$\frac{d y}{d x}=\frac{\log _{10}41. If the parametric equation of curve is given by $$x=\cos \theta+\log \tan \frac{\theta}{2}$$ and $$y=\sin \theta$$, then42. If $$y=(x-1)^2(x-2)^3(x-3)^5$$, then $$\frac{d y}{d x}$$ at $$x=4$$ is equal to43. A particle starts form rest and its angular displacement (in radians) is given by $$\theta=\frac{t^2}{20}+\frac{t}{5}$$.44. If the parabola $$y=\alpha x^2-6 x+\beta$$ passes through the point $$(0,2)$$ and has its tangent at $$x=\frac{3}{2}$$ p45. The function $$f(x)=x^2-2 x$$ is strictly decreasing in the interval46. The maximum slope of the curve $$y=-x^3+3 x^2+2 x-27$$ is47. $$\int \frac{x^3 \sin \left(\tan ^{-1}\left(x^4\right)\right)}{1+x^8} d x$$ is equal to 48. The value of $$\int \frac{x^2 d x}{\sqrt{x^6+a^6}}$$ is equal to49. The value of $$\int \frac{x e^x d x}{(1+x)^2}$$ is equal to50. The value of $$\int e^x\left[\frac{1+\sin x}{1+\cos x}\right] d x$$ is equal to51. If $$I_n=\int_0^{\frac{\pi}{4}} \tan ^n x d x$$, where $$n$$ is positive integer, then $$I_{10}+I_8$$ is equal to52. The value of $$\int_0^{4042} \frac{\sqrt{x} d x}{\sqrt{x}+\sqrt{4042-x}}$$ is equal to53. The area of the region bounded by $$y=-\sqrt{16-x^2}$$ and $$X$$-axis is54. If the area of the ellipse is $$\frac{x^2}{25}+\frac{y^2}{\lambda^2}=1$$ is $$20 \pi$$ sq units, then $$\lambda$$ is55. Solution of differential equating $$x d y-y d x=0$$ represents56. The number of solutions of $$\frac{d y}{d x}=\frac{y+1}{x-1}$$, when $$y(\mathrm{l})=2$$ is57. A vector a makes equal acute angles on the coordinate axis. Then the projection of vector $$\mathbf{b}=5 \hat{\mathbf{i}58. The diagonals of a parallelogram are the vectors $$3 \hat{\mathbf{i}}+6 \hat{\mathbf{j}}-2 \hat{\mathbf{k}}$$. and $$-\h59. If $$\mathbf{a} \cdot \mathbf{b}=0$$ and $$\mathbf{a}+\mathbf{b}$$ makes an angle $$60^{\circ}$$ with $$a$$, then60. If the area of the parallelogram with $$\mathbf{a}$$ and $$\mathbf{b}$$ as two adjacent sides is 15 sq units, then the a
Physics
1. The physical quantity which is measure in the unit of wb $$\mathrm{A}^{-1}$$ is2. What will be the reading in the voltmeter and ammeter of the circuit shown?
3. LC-oscillations are similar and analogous to the mechanical oscillations of a block attached to a spring. The electrical4. In an oscillating $$L C$$-circuit, $$L=3 \mathrm{mH}$$ and $$C=2.7 \mu \mathrm{F}$$. At $$t=0$$, the charge on the capac5. Suppose that the electric field amplitude of electromagnetic wave is $$E_0=120 \mathrm{~NC}^{-1}$$ and its frequency $$f6. The source of electromagnetic wave can be a charge7. In refraction, light waves are bent on passing from one medium to second medium because, in the second medium8. If the refractive index from air to glass is $$\frac{3}{2}$$ and that from air to water is $$\frac{4}{3}$$, then the rat9. Two thin biconvex lenses have focal lengths $$f_1$$ and $$f_2$$. A third thin biconcave lens has focal length of $$f_3$$10. The size of the image of an object, which is at infinity, as formed by a convex lens of focal length $$30 \mathrm{~cm}$$11. A slit of width $$a$$ is illuminated by red light of wavelength $$6500 \mathop A\limits^o$$. If the first diffraction mi12. Which of the following statements are correct with reference to single slit diffraction pattern?
(I) Fringes are of uneq13. In the Young's double slit experiment a monochromatic source of wavelength $$\lambda$$ is used. The intensity of light p14. The work-function of a metal is 1 eV. Light of wavelength $$3000 \mathop A\limits^o$$ is incident on this metal surface.15. A proton moving with a momentum $$p_1$$ has a kinetic energy $$1 / 8$$th of its rest mass-energy. Another light photon h16. According to Einstein's photoelectric equation to the graph between kinetic energy of photoelectrons ejected and the fre17. Energy of an electron in the second orbit of hydrogen atom is $$E_2$$. The energy of electron in the third orbit of $$\m18. The figure shows standing de-Broglie waves due to the revolution of electron in a certain orbit of hydrogen atom. Then, 19. An electron in an excited state of $$\mathrm{Li}^{2+}$$ ion has angular momentum $$\frac{3 h}{2 \pi}$$. The de-Broglie w20. Which graph in the following diagram correctly represents the potential energy of a pair of nucleons as a function of th21. In a nuclear reactor heavy nuclei is not used as moderators because22. The circuit given represents which of the logic operations?
23. Identify the incorrect statement.24. Three photodiodes $$D_1, D_2$$ and $$D_3$$ are made of semiconductors having band gaps of $$2.5 \mathrm{~eV}, 2 \mathrm{25. For a body moving along a straight line, the following $$v$$-$$t$$ graph is obtained.
According to the graph, the displ26. A particle starts from rest. Its acceleration $$a$$ versus time $$t$$ is shown in the figure. The maximum speed of the p27. The maximum range of a gun on horizontal plane is $$16 \mathrm{~km}$$. If $$\mathrm{g}=10 \mathrm{~ms}^{-2}$$, then muzz28. The trajectory of projectile is29. For a projectile motion, the angle between the velocity and acceleration is minimum and acute at30. A particle starts from the origin at $$t=0$$ with a velocity of $$10 \hat{\mathbf{j}} \mathrm{ms}^{-1}$$ and move in the31. A coin placed on a rotating turn table just slips if it is placed at a distance of $$4 \mathrm{~cm}$$ from the centre. I32. A $$1 \mathrm{~kg}$$ ball moving at $$12 \mathrm{~ms}^{-1}$$ collides with a $$2 \mathrm{~kg}$$ ball moving in opposite 33. A ball hits the floor and rebounds after an inelastic collision. In this case34. In figure $$E$$ and $$v_{\mathrm{cm}}$$ represent the total energy and speed of centre of mass of an object of mass $$1 35. Two bodies of masses $$8 \mathrm{~kg}$$ are placed at the vertices $$A$$ and $$B$$ of an equilateral triangle $$A B C$$.36. Two capillary tubes $$P$$ and $$Q$$ are dipped vertically in water. The height of water level in capillary tube $$P$$ is37. Which of the following curves represent the variation of coefficient of volume expansion of an ideal gas at constant pre38. A number of Carnot engines are operated at identical cold reservoir temperatures $$(T_L)$$. However, their hot reservoir39. A gas mixture contains monoatomic and diatomic molecules of 2 moles each. The mixture has a total internal energy of (sy40. A pendulum oscillates simple harmonically and only if
I. the sizer of the bob of pendulum is negligible in comparison wi41. To propagate both longitudinal and transverse waves, a material must have42. A copper rod $$A B$$ of length $$l$$ is rotated about end $$A$$ with a constant angular velocity $$\omega$$. The electri43. Electric field due to infinite, straight uniformly charged wire varies with distance $$r$$ as44. A $$2 \mathrm{~g}$$ object, located in a region of uniform electric field $$\mathrm{E}=\left(300 \mathrm{NC}^{-1}\right)45. If a slab of insulating material (conceptual). $$4 \times 10^{-3} \mathrm{~m}$$ thick is introduced between the plates o46. Eight drops of mercury of equal radii combine to form a big drop. The capacitance of a bigger drop as compared to each s47. Which of the following statements is false in the case of polar molecules?48. An electrician requires a capacitance of $$6 \mu \mathrm{F}$$ in a circuit across a potential difference of $$1.5 \mathr49. In figure, charge on the capacitor is plotted against potential difference across the capacitor. The capacitance and ene50. A wire of resistance $$3 \Omega$$ is stretched to twice its original length. The resistance of the new wire will be51. In the given arrangement of experiment on meter bridge, if $$A D$$ corresponding to null deflection of the galvanometer 52. A copper wire of length $$1 \mathrm{~m}$$ and uniform cross-sectional area $$5 \times 10^{-7} \mathrm{~m}^2$$ carries a 53. Consider an electrical conductor connected across a potential difference $$V$$. Let $$\Delta q$$ be a small charge movin54. A strong magnetic field is applied on a stationary electron. Then, the electron55. Two parallel wires in free space are $$10 \mathrm{~cm}$$ apart and each carries a current of $$10 \mathrm{~A}$$ in the s56. A toroid with thick windings of $$N$$ turns has inner and outer radii $$R_1$$ and $$R_2$$, respectively. If it carries c57. A tightly wound long solenoid has $n$ turns per unit length, a radius $$r$$ and carries a current $$I$$. A particle havi58. Earth's magnetic field always has a horizontal component except at59. Which of the field pattern given below is valid for electric field as well as for magnetic field?60. The current following through an inductance coil of self-inductance $$6 \mathrm{~mH}$$ at different time instants is as
1
KCET 2021
MCQ (Single Correct Answer)
+1
-0
The current following through an inductance coil of self-inductance $$6 \mathrm{~mH}$$ at different time instants is as shown. The emf induced between $$t=20 \mathrm{~s}$$ and $$t=40 \mathrm{~s}$$ is nearly
A
$$2 \times 10^{-2} \mathrm{~V}$$
B
$$3 \times 10^{-2} \mathrm{~V}$$
C
$$4 \times 10^{-3} \mathrm{~V}$$
D
$$30 \times 10^2 \mathrm{~V}$$