1
KCET 2021
MCQ (Single Correct Answer)
+1
-0

Which of the following pairs has both the ions coloured in aqueous solution? [Atomic numbers of

$$\mathrm{Sc}=21, \mathrm{Ti}=22, \mathrm{Ni}=28, \mathrm{Cu}=29, \mathrm{Mn}=25]$$

A
$$\mathrm{Sc}^{3+}, \mathrm{Mn}^{2+}$$
B
$$\mathrm{Ni}^{2+}, \mathrm{Ti}^{4+}$$
C
$$\mathrm{Ti}^{3+}, \mathrm{Cu}^{+}$$
D
$$\mathrm{Mn}^{2+}, \mathrm{Ti}^{3+}$$
2
KCET 2021
MCQ (Single Correct Answer)
+1
-0

For the crystal field splitting in octahedral complexes,

A
the energy of the $$e_g$$ orbitals will decrease by $$(3 / 5) \Delta_o$$ and that of the $$t_{2 g}$$ will increase by $$(2 / 5) \Delta_0$$
B
the energy of the $$e_g$$ orbitals will increase by $$(3 / 5) \Delta_o$$ and that of the $$t_{2 g}$$ will decrease by $$(2/5) \Delta_o$$
C
the energy of the $$e_g$$ orbitals will increase by $$(3 / 5) \Delta_o$$ and that of the $$t_{2 g}$$ will increase by $$(2 / 5) \Delta_0$$
D
the energy of the $$e_g$$ orbitals will decrease by $$(3 / 5) \Delta_0$$ and that of the $$t_{2 g}$$ will decrease by $$(2 / 5) \Delta_0$$
3
KCET 2021
MCQ (Single Correct Answer)
+1
-0

Peroxide effect is observed with the addition of $$\mathrm{HBr}$$ but not with the addition of HI to unsymmetrical alkene because

A
$$\mathrm{H}-\mathrm{I}$$ bond is stronger than $$\mathrm{H}-\mathrm{Br}$$ and is not cleaved by the free radical
B
$$\mathrm{H}-\mathrm{I}$$ bond is weaker than $$\mathrm{H}-\mathrm{Br}$$ bond so that iodine free radicals combine to form iodine molecules
C
Bond strength of $$\mathrm{HI}$$ and $$\mathrm{HBr}$$ are same but free radicals are formed in $$\mathrm{HBr}$$
D
All of the above
4
KCET 2021
MCQ (Single Correct Answer)
+1
-0

The IUPAC name of $$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{CO}_3\right)\right] \mathrm{Cl}$$ is

A
pentaamminecarbonatocobalt (III) chloride
B
carbonatopentamminecobalt (III) chloride
C
pentaamminecarbonatocobaltate (III) chloride
D
pentaammine cobalt (III) carbonate chloride
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