1
IAT (IISER) 2022
MCQ (Single Correct Answer)
+4
-1

An aqueous solution contains 1.0 M of $\mathrm{X}^{2+}$ and 0.001 M of $\mathrm{Y}^2+$ ions at $25^{\circ} \mathrm{C} . \mathrm{X}^{2+}$ and $\mathrm{Y}^{2+}$ ions do not interact with each other. This solution is put in an electrolytic cell and the voltage is gradually increased till a current begins to flow through the cell. The voltage is maintained at this point and a deposit is observed on the cathode. What is the composition of the material deposited on the cathode?

(Given: Atomic weight of $X$ is 63 and $Y$ is 200.)

$$ \begin{aligned} & X^{2+}+2 e^{-} \rightarrow X, E^0=0.35 \\ & Y^{2+}+2 e^{-} \rightarrow Y, E^0=0.40 \mathrm{~V} \end{aligned} $$

( $E^0$ is the standard reduction potential.)

A
Only Y
B
$24 \% X$ and $76 \% Y$ by weight
C
Only X
D
$98 \% X$ and $2 \% Y$ by weight
2
IAT (IISER) 2022
MCQ (Single Correct Answer)
+4
-1

2 g of naphthoic acid (molecular weight $=172 \mathrm{~g} \mathrm{~mol}^{-} 1$ ) dissolved in 20 mL of benzene shows a freezing point depression of 2 K . For benzene, the freezing point depression constant, $K_f=5$ $\mathrm{K} \mathrm{kg} \mathrm{mol}{ }^{-1}$ and the density is $0.88 \mathrm{~g} \mathrm{~mL}^{-1}$. What is the magnitude of the van't Hoff factor?

A
0.605
B
605.0
C
0.688
D
688.0
3
IAT (IISER) 2022
MCQ (Single Correct Answer)
+4
-1
For the reaction involving ideal gases, $A(g)+2 B(g)=2 C(g)+3 D(g)$, which of the following plots is qualitatively correct? ( $K_p$ and $K_c$ are the equilibrium constants in terms of pressure and concentration respectively. $T$ is the absolute temperature.)
A
IAT (IISER) 2022 Chemistry - Chemical Equilibrium Question 1 English Option 1
B
IAT (IISER) 2022 Chemistry - Chemical Equilibrium Question 1 English Option 2
C
IAT (IISER) 2022 Chemistry - Chemical Equilibrium Question 1 English Option 3
D
IAT (IISER) 2022 Chemistry - Chemical Equilibrium Question 1 English Option 4
4
IAT (IISER) 2022
MCQ (Single Correct Answer)
+4
-1
Identify the correct order of the molecules with respect to the magnitude of their dipole moment:
A
IAT (IISER) 2022 Chemistry - Chemical Bonding and Molecular Structure Question 1 English Option 1
B
IAT (IISER) 2022 Chemistry - Chemical Bonding and Molecular Structure Question 1 English Option 2
C
IAT (IISER) 2022 Chemistry - Chemical Bonding and Molecular Structure Question 1 English Option 3
D
IAT (IISER) 2022 Chemistry - Chemical Bonding and Molecular Structure Question 1 English Option 4
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