The following graph is obtained for vapour pressure (in atm) (on $Y$-axis) and $T$ (in K) (on $X$-axis) for aqueous urea solution and water. What is the boiling point (in K) of urea solution?
(Atmospheric pressure $=1 \mathrm{~atm}$ )

Given below are two statements.
Statement I : Liquids $A$ and $B$ form a non-ideal solution with negative deviation. The interactions between $A$ and $B$ are weaker than $A-A$ and $B-B$ interactions.
Statement II : In reverse osmosis, the applied pressure must be higher than the osmotic pressure of solution
The correct answer is
The standard reduction potentials of $2 \mathrm{H}^{+} / \mathrm{H}_2, \mathrm{Cu}^{2+} / \mathrm{Cu}, \mathrm{Zn}^{2+} / \mathrm{Zn}$ and $\mathrm{NO}_3^{-}, \mathrm{H}^{-} / \mathrm{NO}$ are 0.0 0.34 . -0.76 and 0.97 V respectively. Identify the correct statements from the following.
I. $\mathrm{H}^{+}$does not oxidise Cu to $\mathrm{Cu}^{2+}$
II. Zn reduces $\mathrm{Cu}^{2+}$ to Cu
III. $\mathrm{NO}_3^{-}$oxidises Cu to $\mathrm{Cu}^{2+}$