1
IAT (IISER) 2024
MCQ (Single Correct Answer)
+4
-1

The following complex ions absorb in the ultraviolet-visible region of light. Which one of these shows violet colour?

$$ \left[\mathrm{CoCl}\left(\mathrm{NH}_3\right)_5\right]^{2+},\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)\left(\mathrm{NH}_3\right)_5\right]^{3+},\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}, \text { and }\left[\mathrm{Co}(\mathrm{CN})_6\right]^{3-} $$

A
$\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)\left(\mathrm{NH}_3\right)_5\right]^{3+}$
B
$\left[\mathrm{CoCl}\left(\mathrm{NH}_3\right)_5\right]^{2+}$
C
$\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}$
D
$\left[\mathrm{Co}(\mathrm{CN})_6\right]^{3-}$
2
IAT (IISER) 2020
MCQ (Single Correct Answer)
+4
-1
Which one of the following aqueous solutions gives the most intense colour?
A
$0.1 \mathrm{M}\left[\mathrm{Mn}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_2$
B
$0.1 \mathrm{M}\left[\mathrm{Mn}\left(\mathrm{NH}_3\right)_6\right] \mathrm{Cl}_3$
C
$0.1 \mathrm{M}\left[\mathrm{Mn}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{Cl}$
D
$0.1 \mathrm{M} \mathrm{KMnO}_4$
3
IAT (IISER) 2020
MCQ (Single Correct Answer)
+4
-1

$$ \text { The number of unpaired electron(s) in the square planar complex }[\text{Ni}(\text{CN})_4]^{2-} \text { is/are } $$ :

A
2
B
1
C
4
D
0
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