1
IAT (IISER) 2025
MCQ (Single Correct Answer)
+4
-1

Which among the following processes is/are associated with increasing bond order but no change in diamagnetic/paramagnetic behaviour?

(i) $\mathrm{N}_2 \rightarrow \mathrm{~N}_2^{+}+\mathrm{e}^{-}$

(ii) $\mathrm{O}_2 \rightarrow \mathrm{O}_2^{+}+\mathrm{e}^{-}$

(iii) $\mathrm{O}_2+\mathrm{e}^{-} \rightarrow \mathrm{O}_2^{-}$

A

(ii) only

B
(i) and (ii)
C
(ii) and (iii)
D
(iii) only
2
IAT (IISER) 2025
MCQ (Single Correct Answer)
+4
-1

The dipole moments of three $\mathrm{AB}_3$-type molecules $\mathbf{I}, \mathbf{I I}$, and $\mathbf{I I I}$ are measured to be $0.0 \mathrm{D}, 0.2 \mathrm{D}$, and 1.5 D , respectively. Which one of the following options is correct regarding the identity of $\mathbf{I}, \mathbf{I I}$, and $\mathbf{I I I}$ ?

A

I: $\mathrm{BF}_3, \mathbf{I I}: \mathrm{NF}_3, \mathbf{I I I}: \mathrm{NH}_3$

B

I: $\mathrm{BF}_3, \mathbf{I I}: \mathrm{NH}_3, \mathbf{I I I}: \mathrm{NF}_3$

C

I: $\mathrm{ClF}_3, \mathbf{I I}: \mathrm{NF}_3, \mathbf{I I I}: \mathrm{NH}_3$

D

I: $\mathrm{BCl}_3, \mathbf{I I}: \mathrm{NH}_3, \mathbf{I I I}: \mathrm{NF}_3$

3
IAT (IISER) 2024
MCQ (Single Correct Answer)
+4
-1
Which one of the following statements is correct about $\mathrm{N}_2, \mathrm{CO}$, and $\mathrm{NO}^{+}$?
A
These are isoelectronic and have identical bond order.
B
These are isoelectronic and have different bond orders.
C
These are not isoelectronic but have identical bond order.
D
These are neither isoelectronic nor have identical bond order.
4
IAT (IISER) 2024
MCQ (Single Correct Answer)
+4
-1
According to the VSEPR theory, what are the most stable shapes of $X_4 F_4$ and $\mathrm{SF}_4$, respectively?
A
See-saw and square planar
B
Both see-saw
C
Square planar and see-saw
D
Both square planar

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