1
IAT (IISER) 2023
MCQ (Single Correct Answer)
+4
-1
Consider the following reaction: $\mathrm{CH}_4(\mathrm{~g}) \rightarrow \mathrm{C}(\mathrm{g})+4 \mathrm{H}(\mathrm{g}) ; \Delta_a H^0=1665 \mathrm{kJmol}^{-} 1$ Which of the statements is FALSE?
A
$\Delta_a H^0$ is the mean bond enthalpy of a C-H bond.
B
All four $\mathrm{C}-\mathrm{H}$ bonds in $\mathrm{CH}_4$ are identical in bond length and energy.
C
The energy required to break individual $\mathrm{C}-\mathrm{H}$ bonds in successive steps is different.
D
Mean C-H bond enthalpies differ slightly from compound to compound
2
IAT (IISER) 2023
MCQ (Single Correct Answer)
+4
-1
In two solutions $X$ (hexane and benzene) and $Y$ (water and HCl ), what types of deviations from Raoult's law are observed?
A
Positive deviation and no deviation (ideal behaviour), respectively.
B
Negative deviation and positive deviation, respectively.
C
Positive deviation and negative deviation, respectively
D
No deviation (ideal behaviour) and negative deviation, respectively.
3
IAT (IISER) 2023
MCQ (Single Correct Answer)
+4
-1
In aqueous solution, the hydronium ion gets further hydrated to give which of the following species?
A
$\mathrm{H}_3 \mathrm{O}_2^{+}$
B
$\mathrm{H}_5 \mathrm{O}_3{ }^{+}$
C
$\mathrm{H}_7 \mathrm{O}_4^{+}$
D
$\mathrm{H}_9 \mathrm{O}_4^{+}$
4
IAT (IISER) 2023
MCQ (Single Correct Answer)
+4
-1
Let $f: \mathbf{R} \rightarrow(0, \infty)$ be a continuous decreasing function. Suppose $f(0), \dot{f}(1), \ldots, f(10)$ are in a geometric progression with common ratio $\frac{1}{5}$. In which of the following intervals does the value of $\int_0^{10} f(x) d x$ lie?
A
$(0,2 f(0))$
B
$(4 f(0), 6 f(0))$
C
$(8 f(0), 10 f(0))$
D
$(12 f(0), 14 f(0))$
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