WB JEE 2025
Paper was held on Mon, Apr 28, 2025 5:30 AM
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Chemistry

1

The number of lone pair of electrons and the hybridization of Xenon ( Xe ) in $\mathrm{XeOF}_2$ are

2

In the following reaction, the major product $(\mathrm{H})$ is

3

Increasing order of the nucleophilic substitution of following compounds

4

Which of the following hydrocarbons reacts easily with $\mathrm{MeMgBr}$ to give methane?

5

Adiabatic free expansion of ideal gas must be

6

An optically active alkene having molecular formula $\mathrm{C}_8 \mathrm{H}_{16}$ gives acetone as one of the products on ozonolysis. The structure of the alkene is

7

$360 \mathrm{~cm}^3$ of a hydrocarbon diffuses in 30 minutes, while under the same conditions $360 \mathrm{~cm}^3$ of $\mathrm{SO}_2$ gas diffuses in one hour. The molecular formula of the hydrocarbon is

8

The number of terminal and bridging hydrogens in $\mathrm{B}_2 \mathrm{H}_6$ are respectively

9

The major product (F) in the following reaction is

10

For a chemical reaction, half-life period $\left(t_{\frac{1}{2}}\right)$ is 10 minutes. How much reactant will be left after 20 minutes if one starts with 100 moles of reactant and the order of the reaction be (i) zero, (ii) one and (iii) two?

11

Equal volume of two solutions $A$ and $B$ of a strong acid having $\mathrm{pH}=6.0$ and $\mathrm{pH}=4.0$ respectively are mixed together to form a new solution. The pH of the new solution will be in the range

12

$P$ and $Q$ combines to form two compounds $\mathrm{PQ}_2$ and $\mathrm{PQ}_3$. If $1 \mathrm{~g} ~\mathrm{PQ}{ }_2$ is dissolved in 51 g benzene the depression of freezing point becomes $0 \cdot 8^{\circ} \mathrm{C}$. On the other hand if $1 \mathrm{~g} ~\mathrm{PQ}_3$ is dissolved in 51 g of benzene, the depression of freezing point becomes $0.625^{\circ} \mathrm{C}$. The atomic mass of P and Q are $\left(\mathrm{K}_{\mathrm{f}}\right.$ of benzene $=5 \cdot 1 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1})$

13

Identify the major product (G) in the following reaction

14

Increasing order of solubility of AgCl in (i) $\mathrm{H}_2 \mathrm{O}$, (ii) 1 M NaCl (aq.), (iii) 1 M CaCl 2 (aq.) and (iv) $1 \mathrm{M}~ \mathrm{NaNO}_3$ (aq.) solution

15

Arrange the following compounds in order of their increasing acid strength

16

Which of the following hydrogen bonds is likely to be the weakest?

17

How many oxygen atoms are present in 0.36 g of a drop of water at STP?

18

The molar conductances of $\mathrm{Ba}(\mathrm{OH})_2, \mathrm{BaCl}_2$ and $\mathrm{NH}_4 \mathrm{Cl}$ at infinite dilution are $523 \cdot 28,280 \cdot 0$ and $129.8 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}$ respectively. The molar conductance of $\mathrm{NH}_4 \mathrm{OH}$ at infinite dilution will be

19

The common stable oxidation states of Eu and Gd are respectively

20

Which one among the following compounds will most readily be dehydrated under acidic condition?

21

$$\begin{aligned} &{ }_5 \mathrm{~B}^{10}+{ }_2 \mathrm{He}^4 \rightarrow \mathrm{X}+{ }_0 \mathrm{n}^1\\ &\text { In the above nuclear reaction ' } X \text { ' will be } \end{aligned}$$

22

An LPG (Liquified Petroleum Gas) cylinder weighs 15.0 kg when empty. When full, it weighs 30.0 kg and shows a pressure of 3.0 atm . In the course of usage at $27^{\circ} \mathrm{C}$, the mass of the full cylinder is reduced to $24 \cdot 2 \mathrm{~kg}$. The volume of the used gas in cubic metre at the normal usage condition ( atm and $27^{\circ} \mathrm{C}$ ) is (assume LPG to be normal butane and it behaves ideally)

23

What is the four-electron reduced form of $\mathrm{O}_2$ ?

24

Kjeldahl's method cannot be used for the estimation of nitrogen in which compound?

25

Which of the following compounds is most reactive in $\mathrm{S}_{\mathrm{N}} 1$ reaction?

26

The coagulating power of electrolytes having ions $\mathrm{Na}^{+}, \mathrm{Al}^{3+}$ and $\mathrm{Ba}^{2+}$ for $\mathrm{As}_2 \mathrm{S}_3$ sol increases in the order

27

If three elements $A, B, C$ crystalise in a cubic solid lattice with $B$ atoms at the cubic centres, $C$ aton at the centre of edges and A atoms at the corners, then formula of the compound is

28

Which of the following oxides is paramagnetic?

29

How many electrons are needed to reduce $\mathrm{N}_2$ to $\mathrm{NH}_3 ?$

30

The bond order of $\mathrm{HeH}^{+}$is

31

An egg takes 4.0 minutes to boil at sea level where the boiling point of water is $T_1 K$, where as it takes 8.0 minutes to boil on a mountain top where the boiling point of water is $\mathrm{T}_2 \mathrm{~K}$. The activation energy for the reaction that takes place during the boiling of egg is

32

As per the following equation, 0.217 g of HgO (molecular mass $=217 \mathrm{~g} \mathrm{~mol}^{-1}$ ) reacts with excess iodide. On titration of the resulting solution, how many mL of 0.01 M HCl is required to reach the equivalence point?

$\mathrm{HgO}+4 \mathrm{I}^{-}+\mathrm{H}_2 \mathrm{O} \longrightarrow \mathrm{HgI}_4{ }^{2-}+2 \mathrm{OH}^{-}$

33

The major product 'P' and 'Q' in the above reactions are

34

Consider the following gas phase dissociation, $\mathrm{PCl}_5(\mathrm{~g}) \rightleftharpoons \mathrm{PCl}_3(\mathrm{~g})+\mathrm{Cl}_2(\mathrm{~g})$ with equilibrium constant $K_P$ at a particular temperature and at pressure $P$. The degree of dissociation ( $\alpha$ ) for $\mathrm{PCl}_5(\mathrm{~g})$ is

35

Compound given below will produce effervescence when mixed with aqueous sodium bicarbonate solution

36

Which of the following statement(s) is/are correct about the given compound?

37

$X$ is an extensive property and $x$ is an intensive property of a thermodynamic system. Which of the following statement(s) is (are) correct?

38

Which pair of ions among the following can be separated by precipitation method?

39

The compound(s) showing optical activity is/are

40

Identify 'P' and 'Q' in the following reaction

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