Among the following transition metal ions, how many have the same number of unpaired electrons, and thus approximately the same magnetic moment?
(i) $\mathrm{Cr}^{3+}$
(ii) $\mathrm{Fe}^{3+}$
(iii) $\mathrm{Mn}^{2+}$
(iv) $\mathrm{Co}^{2+}$
(v) $\mathrm{Ni}^{2+}$
1
2
3
4
The $\mathrm{Fe}^{3+}$ ion, having five unpaired electrons, shows a spin-only magnetic moment closest to
4
5
6
7
The hybridisation and geometry of the complex $\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}$ are
$s p^3 d$ and tetrahedral
$s p^3$ and square planar
$s p^3$ and tetrahedral
$d s p^2$ and square planar
Match List-I with List-II for oxidation number of central metal atom.
$$ \begin{array}{llcc} \hline \begin{array}{c} \text { List-I } \\ (\text { Complex }) \end{array} & & \begin{array}{c} \text { List-II } \\ \text { (Oxidation number) } \end{array} \\ \hline \text { A. } \mathrm{Ni}(\mathrm{CO})_4 & \text { I. } & +1 \\ \hline \text { B. }\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_5 \mathrm{NO}\right]^{2+} & \text { II. } & \text { Zero } \\ \hline \begin{array}{l} \text { C. }\left[\mathrm{Co}(\mathrm{CO})_5\right]^{2-} \\ (\mathrm{Each} \mathrm{Cr}) \end{array} & \text { III. } & -1 \\ \hline \begin{array}{l} \text { D. }\left[\mathrm{Cr}(\mathrm{CO})_{10}\right]^{2-} \\ (\mathrm{Each}) \end{array} & \text { IV. } & -2 \\ \hline \end{array} $$
Choose the correct match from the options given below
A-II, B-I, C-IV, D-III
A-II, B-IV, C-I, D-III
A-II, B-III, C-I, D-IV
A-I, B-II, C-IV, D-III
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